sodium hydroxide in water Fe complex stirred vigorously in Et2O with aq. NaOH soln. for 10 min; separation of layers, washing with H2O, drying over MgSO4, evapn.;
参考文献
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, , vol. 11, p. 695 - 705
sodium hydroxide in water; acetonitrile soln. of Fe complex in acetonitrile treated with aq. soln. of NaOH for 0.5 h; addn. of H2O, extn. (Et2O), washing with H2O, drying over MgSO4, evapn.;
参考文献
Cully, Norman; Watts, William E.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1981 , vol. 11, p. 695 - 705
sodium hydroxide in water; acetonitrile soln. of Fe complex in acetonitrile treated with aq. soln. of NaOH for 0.5 h; addn. of H2O, extn. (Et2O), washing with H2O, drying over MgSO4, evapn.;
参考文献
Cully, Norman; Watts, William E.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1981 , vol. 11, p. 695 - 705
trichlorophosphate in not given Vilsmeyer formylation;;
参考文献
Rosenblum, M.
Chemistry and Industry (London, United Kingdom), 1957 , p. 72 - 72
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Gmelin Handbook: Fe: Org.Verb.A1, 2.5.7.7, page 161 - 162
NaOOCCH3 in methanol; toluene soln. of NaOAc in MeOH added to suspn. of Pt-complex and Fe-complex in toluene, mixt. refluxed for 3 days; toluene:methanol=20:5 and molar ratioof Fe(II):Pt(II):NaOAc = 1:1:2; filtered, filtrate concd. to dryness, residue dissolved in CH2Cl2, column chromy. (SiO2, CH2Cl2);
in benzene soln. of ferrocenylcarbinol is degassed (N2) and refluxed for 30 h in presence of Fe2(CO)9; react. mixt. is filtered over Celite, concd. and chromatographed (silica gel 60, CH2Cl2);
参考文献
Journal of Organometallic Chemistry, , vol. 379, p. 129 - 138
