反应条件
n-butyllithium in diethyl ether; hexane n-BuLi (2.5 M, hexane) was added to ethereal soln. of C6F3BrH2 at -60 °C, keeping at this temp., 1.5 equiv. of cold (-70 °C) B(OMe)3 was added in ether, mixt. was stirred for 1 h at -60 °C, warmed up to 20 °C within 1 h; poured into 5 percent HCl, org. layer was sepd., aq. layer was twice extd. with ether, extracts were combined, dried with MgSO4, evapn., recrystn. from hot toluene, elem. anal.;
参考文献
Frohn; Adonin; Bardin; Starichenko
Zeitschrift fur Anorganische und Allgemeine Chemie, 2002 , vol. 628, # 13 p. 2827 - 2833
