hydrogen in gas
byproducts: C2H2, C2H4; 5percent B(OCH3)3 in H2 passed through microwave discharge (pressure dropped from 25.5 torr to 18 torr); product fractionated by trap-to-trap distillation;
参考文献
Jeffers, Peter M.; Bauer, S. H.
Inorganic Chemistry, 1981 , vol. 20, p. 1698 - 1701
1: 2-(1-adamantyl)-4-bromo-1-methoxybenzene With magnesium; ethylene dibromide in tetrahydrofuran
RefluxInert atmosphere;
2: boric acid trimethyl ester in tetrahydrofuran
T=-50 - -40°C; 0.5 h; Inert atmosphere;
3: With hydrogenchloride; water in tetrahydrofuran
参考文献
Kalvinsh, Ivars; Chernobrovijs, Aleksandrs; Tribulovich, Vyacheslav; Labeish, Vladimir
Patent: US2010/113816 A1, 2010 ;
Location in patent: Page/Page column 3 ;
1: 2-bromo-9,10-diphenylanthracene With n-butyllithium in tetrahydrofuran
T=-78°C; 1 h;
2: boric acid trimethyl ester in tetrahydrofuran
T=20°C; 4 h;
3: With hydrogenchloride in tetrahydrofuran; water
参考文献
Samsung Mobile Display Co., Ltd.
Patent: EP2292604 A2, 2011 ;
Location in patent: Page/Page column 22 ;
