1.4-(CH3O2C)2C6H4Cr(CO)3; hydrogen in cyclohexane T=170°C; P=31028.9 Torr; 30 h; var. ligands in complexes of methyl benzoate Cr(CO)2L, var. reaction times; Product distribution;
Parahydrogen (about; lt;Rh(2,5-norbornadiene)(PPh3)gt;*PF6 in acetone Ambient temperature; Mechanism;
参考文献
Hermans, Sophie; Raja, Robert; Thomas, John M.; Johnson, Brian F. G.; Sankar, Gopinathan; Gleeson, David
Angewandte Chemie - International Edition, 2001 , vol. 40, # 7 p. 1211 - 1215
Barlow, Michael G.; Sibous, Lakhdar; Suliman, Nadia N. E.; Tipping, Anthony E.
Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 6 p. 519 - 524
PdCl2 was dissolved in conc. HCl by stirring at 150°C for 1 h, cooled to room temp., diluted with EtOH, filtered, ligand was added with stirring; filtered, washed with Et2O, recrystd. from CH2Cl2, dried at room temp. under vac; elem. anal.;
参考文献
Madan; Anand; Varma
Journal of Thermal Analysis and Calorimetry, 2000 , vol. 59, # 1 p. 531 - 539
in water; acetone Kinetics; reaction in an aq. acetone soln. at 25°C; followed by UV and (1)H NMR;
参考文献
Sarhan, Jamil K. K.; Murray, Siew-Wan Foong; Asfour, Hasan M.; Green, Michael; Wing, Richard M.; Parra-Haake, Miguel
Inorganic Chemistry, 1986 , vol. 25, p. 243 - 244
