tannase; water in toluene T=20 - 35°C; ΔrHmo, ΔrGmo, ΔrSmo, reaction time 6-7 d, other reagents: K2HPO4, H3PO4; CH3COONa, CH3COOH; NaOH, 2-(N-morpholino)ethanesulfonic acid; reaction in aq. soln. at various pH, other reaction time; Equilibrium constantThermodynamic data;
参考文献
Tewari; Schantz; Rekharsky; Goldberg
Journal of Chemical Thermodynamics, 1996 , vol. 28, # 2 p. 171 - 185
1: 99 percent / K2CO3 / dimethylformamide / 5 h / 75 °C
2: 95 percent / LiAlH4 / tetrahydrofuran / 0 - 20 °C
View Scheme
参考文献
Percec, Virgil; Peterca, Mihai; Sienkowska, Monika J.; Ilies, Marc A.; Aqad, Emad; Smidrkal, Jan; Heiney, Paul A.
Journal of the American Chemical Society, 2006 , vol. 128, # 10 p. 3324 - 3334
1: 99 percent / K2CO3 / dimethylformamide / 5 h / 75 °C
2: 95 percent / LiAlH4 / tetrahydrofuran / 0 - 20 °C
3: pyridinium chlorochromate / CH2Cl2 / 20 °C
View Scheme
参考文献
Percec, Virgil; Peterca, Mihai; Sienkowska, Monika J.; Ilies, Marc A.; Aqad, Emad; Smidrkal, Jan; Heiney, Paul A.
Journal of the American Chemical Society, 2006 , vol. 128, # 10 p. 3324 - 3334
