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乙二醇
甲醛
63148-62-9
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丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
121045-39-4
合成路线
（共 8 条）
71031-48-6
4-羟基-3-碘联苯
+
536-74-3
苯乙炔
→
反应条件
121045-39-4
反应条件
triethylamine in water T=80°C; 20 h;
参考文献
Ohtaka, Atsushi; Teratani, Takuto; Fujii, Ryohei; Ikeshita, Kanako; Kawashima, Takahiro; Tatsumi, Koichi; Shimomura, Osamu; Nomura, Ryoki
Journal of Organic Chemistry, 2011 , vol. 76, # 10 p. 4052 - 4060
1448818-05-0
+
603-33-8
三苯基铋
→
反应条件
92-52-4
联苯
+
121045-39-4
反应条件
tetrakis(triphenylphosphine) palladium(0); caesium carbonate in N,N-dimethyl-formamide T=90°C; 4 h; Inert atmosphereSchlenk technique; chemoselective reaction;
参考文献
Rao, Maddali L. N.; Jadhav, Deepak N.; Dasgupta, Priyabrata
European Journal of Organic Chemistry, 2013 , # 4 p. 781 - 788
1719-19-3
2-甲基-4-苯基-3-丁炔-2-醇
+
71031-48-6
4-羟基-3-碘联苯
→
反应条件
121045-39-4
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; potassium tert-butylate; silica gel in dimethyl sulfoxide T=20 - 110°C; 0.05 h; Inert atmosphereMicrowave irradiation;
参考文献
Wu, Liansheng; Shi, Xiaokang; Xu, Xiaoyun; Liang, Fen; Huang, Guosheng
Journal of Chemical Sciences, 2011 , vol. 123, # 5 p. 697 - 702
1191415-07-2
+
2996-92-1
苯基三甲氧基硅烷
→
反应条件
121045-39-4
反应条件
tetrabutyl ammonium fluoride; palladium diacetate; triphenylphosphine in 1-methyl-pyrrolidin-2-one T=80°C; tandem elimination-addition-Hiyama coupling; 24 h;
参考文献
Liu, Jie; Chen, Wei; Ji, Yong; Wang, Lei
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 8 p. 1585 - 1592
66502-11-2
→
反应条件
121045-39-4
反应条件
1: 74 percent / NaBH4 / methanol / 6 h / Ambient temperature 2: 84 percent / pyridine / CH2Cl2 / 20 h / Ambient temperature 3: 1) sulphuryl chloride; 2) triethylamine / 1) CH2Cl2, -40 deg C, 20 min; 2) CH2Cl2, DMF, -40 to 20 deg C 4: conc. HCl / 2-methoxy-ethanol / 4 h / Heating View Scheme
参考文献
Ota, Tomomi; Hasegawa, Shun; Inoue, Seiichi; Sato, Kikumasa
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1988 , p. 3029 - 3036
121045-46-3
→
反应条件
121045-39-4
反应条件
1: 84 percent / pyridine / CH2Cl2 / 20 h / Ambient temperature 2: 1) sulphuryl chloride; 2) triethylamine / 1) CH2Cl2, -40 deg C, 20 min; 2) CH2Cl2, DMF, -40 to 20 deg C 3: conc. HCl / 2-methoxy-ethanol / 4 h / Heating View Scheme
参考文献
Ota, Tomomi; Hasegawa, Shun; Inoue, Seiichi; Sato, Kikumasa
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1988 , p. 3029 - 3036
121045-17-8
→
反应条件
121045-39-4
反应条件
1: 1) sulphuryl chloride; 2) triethylamine / 1) CH2Cl2, -40 deg C, 20 min; 2) CH2Cl2, DMF, -40 to 20 deg C 2: conc. HCl / 2-methoxy-ethanol / 4 h / Heating View Scheme
参考文献
Ota, Tomomi; Hasegawa, Shun; Inoue, Seiichi; Sato, Kikumasa
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1988 , p. 3029 - 3036
532-27-4
2-氯苯乙酮
→
反应条件
121045-39-4
反应条件
1: 1) NaOH / 1) MeOH, 0 deg C, 20 min 2) MeOH, RT, 6 h 2: 74 percent / NaBH4 / methanol / 6 h / Ambient temperature 3: 84 percent / pyridine / CH2Cl2 / 20 h / Ambient temperature 4: 1) sulphuryl chloride; 2) triethylamine / 1) CH2Cl2, -40 deg C, 20 min; 2) CH2Cl2, DMF, -40 to 20 deg C 5: conc. HCl / 2-methoxy-ethanol / 4 h / Heating View Scheme
参考文献
Ota, Tomomi; Hasegawa, Shun; Inoue, Seiichi; Sato, Kikumasa
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1988 , p. 3029 - 3036
