in dichloromethane byproducts: PC(C6H2(C(CH3)3)3); (Ar); mixt. is stirred at room temp. for 12 h; solvent is evapd. under vacuum, residue is extd. with hexanes, filtn. (Celite), volume is reduced, crystn. at -78°C;
in deuterated toluene to soln. Pt(Ph3P)2(H2C=CH2) in toluene-d8 at room temp. was added soln. ClB(C6F5)2 in toluene-d8, after agitation, 24 h under inert atm.; identified by NMR;
in dichloromethane byproducts: PC(C6H2(C(CH3)3)3); (Ar); mixt. is stirred at room temp. for 12 h; solvent is evapd. under vacuum, residue is extd. with hexanes, filtn. (Celite), volume is reduced, crystn. at -78°C;
in deuterated toluene to soln. Pt(Ph3P)2(H2C=CH2) in toluene-d8 at room temp. was added soln. ClB(C6F5)2 in toluene-d8, after agitation, 24 h under inert atm.; identified by NMR;
triphenylphosphine in neat (no solvent) byproducts: C2H4; heated (30 min, 100°C);
参考文献
Bashilov, V. V.; Sokolov, V. I.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1986 , vol. 35, p. 1079 - 1080
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1986 , p. 1188 - 1189
