三羰基五甲基环戊二烯基铼合成路线 （共 27 条）
反应条件
in hexane
detected by IR;
参考文献
Einstein, Frederick W. B.; Klahn-Oliva, A. Hugo; Sutton, Derek; Tyers, Kenneth G.
Organometallics, 1986 , vol. 5, p. 53 - 59
反应条件
in benzene-d6
byproducts: toluene-4-d, methane; Irradiation (UV/VIS); NMR tube, CO atmosphere (1 atm); irradn. (200 W Hg lamp, 20 min); detd. by (1)H NMR spectroscopy;
参考文献
Leiva, Carmen; Klahn, A. Hugo; Godoy, Fernando; Toro, Adriana; Manriquez, Victor; Wittke, Oscar; Sutton, Derek
Organometallics, 1999 , vol. 18, # 3 p. 339 - 347
反应条件
in pentane
byproducts: benzene, methane; Irradiation (UV/VIS); CO atmosphere, 1 atm; irradn. (200 W Hg lamp, room temp., 20 min);
参考文献
Leiva, Carmen; Klahn, A. Hugo; Godoy, Fernando; Toro, Adriana; Manriquez, Victor; Wittke, Oscar; Sutton, Derek
Organometallics, 1999 , vol. 18, # 3 p. 339 - 347
参考文献
Zobi, Fabio; Spingler, Bernhard; Alberto, Roger
European Journal of Inorganic Chemistry, 2008 , # 27 p. 4205 - 4214
反应条件
in toluene
Ar-atmosphere; stirring equimolar amts. (room temp., 65 h); evapn., dissoln. in PhMe, chromy. (Al2O3, petroleum ether/Et2O=25:1, then 3:1); elem. anal.;
参考文献
Scherer, Otto J.; Ehses, Markus; Wolmershaeuser, Gotthelf
Journal of Organometallic Chemistry, 1997 , vol. 531, # 1-2 p. 217 - 221
反应条件
in dichloromethane
standard Schlenk techniques; Re-compd. dissolved in CH2Cl2 at room temp.under N2, stirred for 5 h with CH3NH2; solvent pumped off, chromy. (alumina, hexane-CH2Cl2 (1:1)), elem. anal.;
参考文献
Aballay, Alvaro; Buono-Core, Gonzalo E.; Godoy, Fernando; Klahn, A. Hugo; Ibanez, Andres; Garland, Maria Teresa
Journal of Organometallic Chemistry, 2009 , vol. 694, # 23 p. 3749 - 3752
反应条件
in dichloromethane
standard Schlenk techniques; Re-compd. dissolved in CH2Cl2 at room temp.under N2, stirred for 5 h with C3H7NH2; solvent pumped off, crystallized from hexane-CH2Cl2, elem. anal.;
参考文献
Aballay, Alvaro; Buono-Core, Gonzalo E.; Godoy, Fernando; Klahn, A. Hugo; Ibanez, Andres; Garland, Maria Teresa
Journal of Organometallic Chemistry, 2009 , vol. 694, # 23 p. 3749 - 3752
反应条件
in not given
Irradiation (UV/VIS); 500 W Hg lamp;
参考文献
Ball, Richard G.; Campen, Andrew K.; Graham, William A. G.; Hamley, Paul A.; Kazarian, Sergei G.; Ollino, Mario A.; Poliakoff, Martyn; Rest, Antony J.; Sturgeoff, Lynda; Whitwell, Ian
Inorganica Chimica Acta, 1997 , vol. 259, # 1-2 p. 137 - 149
反应条件
in further solvent(s)
Kinetics; byproducts: Xe; 25 °C, in supercritical Xe; not isolated, detected by infrared spectroscopy;
参考文献
Grills, David C.; Sun, Xue Z.; Childs, Gavin I.; George, Michael W.
Journal of Physical Chemistry A, 2000 , vol. 104, # 18 p. 4300 - 4307
反应条件
in further solvent(s)
Kinetics; byproducts: Kr; 25 °C, in supercritical Kr; not isolated, detected by infrared spectroscopy;
参考文献
Grills, David C.; Sun, Xue Z.; Childs, Gavin I.; George, Michael W.
Journal of Physical Chemistry A, 2000 , vol. 104, # 18 p. 4300 - 4307
