三羰基五甲基环戊二烯基铼合成路线 （共 27 条）
反应条件
in toluene
Ar-atmosphere; addn. of 2 equiv. C2Ph2 to Re-complex soln. at -78°C, slow warming to room temp.; evapn. (after 4 d), dissoln. in PhMe, chromy. (Al2O3, petroleum ether/PhMe=5:1, then 2:1), evapn., crystn. (CH2Cl2/hexane, -20°C); elem. anal.;
参考文献
Scherer, Otto J.; Ehses, Markus; Wolmershaeuser, Gotthelf
Journal of Organometallic Chemistry, 1997 , vol. 531, # 1-2 p. 217 - 221
反应条件
in cyclohexane
Irradiation (UV/VIS); 500 W Hg lamp; molar ratio Re-:Re2-complex=2:1, total conversion 75percent;
参考文献
Ball, Richard G.; Campen, Andrew K.; Graham, William A. G.; Hamley, Paul A.; Kazarian, Sergei G.; Ollino, Mario A.; Poliakoff, Martyn; Rest, Antony J.; Sturgeoff, Lynda; Whitwell, Ian
Inorganica Chimica Acta, 1997 , vol. 259, # 1-2 p. 137 - 149
反应条件
in benzene-d6
Irradiation (UV/VIS); NMR tube, CO atmosphere (1 atm); irradn. (200 W Hg lamp, 45 min); detd. by (1)H NMR spectroscopy;
参考文献
Leiva, Carmen; Klahn, A. Hugo; Godoy, Fernando; Toro, Adriana; Manriquez, Victor; Wittke, Oscar; Sutton, Derek
Organometallics, 1999 , vol. 18, # 3 p. 339 - 347
反应条件
in benzene-d6
byproducts: C6D5CH3; Irradiation (UV/VIS); NMR tube, CO atmosphere (1 atm); irradn. (200 W Hg lamp, 25 min); detd. by (1)H NMR spectroscopy;
参考文献
Leiva, Carmen; Klahn, A. Hugo; Godoy, Fernando; Toro, Adriana; Manriquez, Victor; Wittke, Oscar; Sutton, Derek
Organometallics, 1999 , vol. 18, # 3 p. 339 - 347
反应条件
in benzene-d6
byproducts: C6D5CH3; Irradiation (UV/VIS); NMR tube, CO atmosphere (1 atm); irradn. (200 W Hg lamp, 25 min); detd. by (1)H NMR spectroscopy;
参考文献
Leiva, Carmen; Klahn, A. Hugo; Godoy, Fernando; Toro, Adriana; Manriquez, Victor; Wittke, Oscar; Sutton, Derek
Organometallics, 1999 , vol. 18, # 3 p. 339 - 347
反应条件
in not given
Irradiation (UV/VIS); irradiation of Re-complex in presence of MeCN;
参考文献
Hoyano, James K.; Graham, William A. G.
Journal of the Chemical Society, Chemical Communications, 1982 , # 1 p. 27 - 28
反应条件
in neat (no solvent)
vac.; heating (150-210°C, several h);
参考文献
Fischer, Ernst Otto; Apostolidis, Christos; Dornberger, Ernst; Filippou, Alexander C.; Kanellakopulos, Basil; et al.
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1995 , vol. 50, # 9 p. 1382 - 1395
