7-溴-9,9-二甲基芴-2-硼酸合成路线 (共 4 条)
反应条件
1: 2,2’-dibromo-9,9’-dimethyl-fluorene With n-butyllithium in diethyl ether; hexane T=-78 - 20°C; 2: tri-isopropoxy-borane in diethyl ether; hexane T=-78 - 20°C; 3: water in diethyl ether; hexane
参考文献
Samsung Mobile Display Co., Ltd.
Patent: EP2149555 A1, 2010 ;
Location in patent: Page/Page column 20 ;
反应条件
1: 2,2’-dibromo-9,9’-dimethyl-fluorene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; Inert atmosphere; 2: boric acid trimethyl ester in tetrahydrofuran; hexane 12 h; 3: With hydrogenchloride in tetrahydrofuran; hexane; water
参考文献
ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD.; LEE, Soo Yong; CHO, Young Jun; KWON, Hyuck Joo; KIM, Sung Min; KIM, Bong Ok
Patent: WO2011/136520 A1, 2011 ;
Location in patent: Page/Page column 10; 11 ;
反应条件
1: boric acid trimethyl ester; 2,2’-dibromo-9,9’-dimethyl-fluorene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 2: hydrogenchloride in tetrahydrofuran; hexane
参考文献
ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD; LEE, Soo Young; CHO, Young Jun; KIM, Bong Ok; KIM, Sung Min
Patent: WO2012/15265 A1, 2012 ;
Location in patent: Page/Page column 19-20 ;
反应条件
potassium carbonate; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; water T=80°C; 5 h;
参考文献
EP2149555 A1, ;
Page/Page column 21 ;