(二环[2.2.1]庚-2,5-二烯)四羰基钼合成路线 （共 39 条）
反应条件
in tetrahydrofuran (Ar); THF added to Mo(CO)6; refluxed (24 h); norbornadiene added; refluxed (40 h, temp. not exceeding 90°C); cooled to room temp.; solvent removed (vac.); extd. (hexane); filtered (Celite); crystn. on cooling;
参考文献
Inorganic Chemistry, , vol. 31, p. 1487 - 1493
反应条件
CO in solid matrix Irradiation (UV/VIS); irradn. of in an Ar-diluted CO matrix at 12 K; not isolated, IR spect.;
参考文献
Journal of Organometallic Chemistry, , vol. 382, # 1-2 p. 201 - 224
反应条件
in benzene-d6 Kinetics; byproducts: 1,5-hexadiene; (N2); in NMR tube; added an excess of norbornadiene to soln. of Mo-complex at 18°C; (1)H NMR;
参考文献
Organometallics, , vol. 10, p. 1627 - 1630
反应条件
norborn-2-ene; deuterium in polyethylene byproducts: d2-norbornane, d2-norbornene, d2-nortricyclene; Irradiation (UV/VIS); complex irradiated under a pressure of D2 and in the presence of excess norbornene at room temp.; not isolated, detected by FTIR;
参考文献
Grevels, Friedrich-Wilhelm; Jacke, Juergen; Koltzbuecher, Werner E.; Schaffner, Kurt; Hooker, Richard H.; Rest, Antony J.
Journal of Organometallic Chemistry, 1990 , vol. 382, # 1-2 p. 201 - 224
反应条件
in tetrahydrofuran reaction in a calorimeter; CO pressure: 500 psi;
参考文献
Mukerjee, Shakti L.; Nolan, Steven P.; Hoff, Carl D.; Lopez de la Vega, Ramon
Inorganic Chemistry, 1988 , vol. 27, p. 81 - 85
反应条件
CO in solid matrix Irradiation (UV/VIS); irradn. of Mo(CO)4(η4-norbornadiene) in a CO matrix a 12 K; detn. of Mo(CO)5(eta.2-norbornadiene) and Mo(CO)6 (both not isolated) by IR spect.;
参考文献
Grevels, Friedrich-Wilhelm; Jacke, Juergen; Koltzbuecher, Werner E.; Schaffner, Kurt; Hooker, Richard H.; Rest, Antony J.
Journal of Organometallic Chemistry, 1990 , vol. 382, # 1-2 p. 201 - 224
反应条件
CO in solid matrix Irradiation (UV/VIS); irradn. in an Ar-diluted CO matrix at 12 K; not isolated, IR spect.;
参考文献
Grevels, Friedrich-Wilhelm; Jacke, Juergen; Koltzbuecher, Werner E.; Schaffner, Kurt; Hooker, Richard H.; Rest, Antony J.
Journal of Organometallic Chemistry, 1990 , vol. 382, # 1-2 p. 201 - 224
反应条件
in hexane N2-atmosphere; ambient temp. or refluxing; not isolated, detd. by IR spectroscopy;
参考文献
Shaw, Bernard L.; Thornton-Pett, Mark; Vessey, Jonathan D.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1994 , # 24 p. 3597 - 3606
参考文献
Sellmann, Dieter; Binker, Gerhard; Schwarz, Joerg; Knoch, Falk; Boese, Roland; et al.
Journal of Organometallic Chemistry, 1987 , vol. 323, p. 323 - 338
反应条件
in tetrahydrofuran reaction in a calorimeter; CO pressure: 500 psi;
参考文献
Inorganic Chemistry, , vol. 27, p. 81 - 85
