(R)-(-)-1,3-壬烷二醇合成路线 （共 14 条）
反应条件
1.1: 87 percent / NaH / dimethylformamide / 6 h / 20 °C 2.1: O3; O2; MeOH / CH2Cl2 / 0 °C 2.2: 95 percent / NaBH4 / CH2Cl2 / 3 h / 20 °C 3.1: NaNO2; H2SO4 / H2O / 0 °C 4.1: 0.02 g / benzene / 1.5 h / 27 °C / UV-irradiation View Scheme
参考文献
Chemistry of Natural Compounds, , vol. 41, # 6 p. 643 - 649
反应条件
1.1: Et3N / cooling 2.1: 50 percent / LiAlH4 / tetrahydrofuran; diethyl ether / 3 h / 20 °C 3.1: 87 percent / NaH / dimethylformamide / 6 h / 20 °C 4.1: O3; O2; MeOH / CH2Cl2 / 0 °C 4.2: 95 percent / NaBH4 / CH2Cl2 / 3 h / 20 °C 5.1: NaNO2; H2SO4 / H2O / 0 °C 6.1: 0.02 g / benzene / 1.5 h / 27 °C / UV-irradiation View Scheme
参考文献
Chemistry of Natural Compounds, , vol. 41, # 6 p. 643 - 649
反应条件
Multistep reaction. Further byproducts.;
参考文献
Chemistry of Natural Compounds, , vol. 41, # 6 p. 643 - 649
反应条件
1: 80 percent / pyridine / cooling 2: 75 percent / LiAlH4 / various solvent(s) / 0 - 20 °C 3: NaNO2; H2SO4 / H2O / 0 °C 4: 0.02 g / benzene / 1.5 h / 27 °C / UV-irradiation View Scheme
参考文献
Ishmuratov; Kharisov; Shayakhmetova; Botsman; Shitikova; Tolstikov
Chemistry of Natural Compounds, 2005 , vol. 41, # 6 p. 643 - 649
