(2S,3R)-3-苯基环氧乙烷-2-甲醛合成路线 (共 2 条)
反应条件
sodium tetrahydroborate Reduction;
参考文献
Zhao, Gui-Ling; Dziedzic, Pawel; Ibrahem, Ismail; Cordova, Armando
Synlett, 2006 , # 20 p. 3521 - 3524
反应条件
Multi-step reaction with 2 steps 1: 82 percent / tert-butyl hydroperoxide; (-)-diethyl D-tartarate; molecular sieves 4 Angstroem / titanium(IV) isopropoxide / CH2Cl2; toluene / 4 h / -23 °C2: oxalyl chloride; dimethylsulfoxide; triethylamine / CH2Cl2 / -78 - 0 °C
参考文献
Yadav, Jhillu Singh; Raju, Atcha Krishnam; Rao, Ponugoti Purushothama; Rajaiah, Gurram Tetrahedron Asymmetry, 2005 , vol. 16, # 19 p. 3283 - 3290