copper(II) nitrate in not given
byproducts: Cu, Cu-phosphide; addition of white P into a warm Cu(NO3)2-soln. yields in formation of nitrous gases, H3PO3, H3PO4 and H4P2O6 and in pptn. of Cu and Cu-phos- pide; mechanism given;;
Cu(II)-sulfate or -formate or -phosphate or -hypo-; phosphate or CuO or Cu2Cl2 in not given
byproducts: Cu, Cu-phosphide; addition of white P into a warm Cu(II)-soln. yields in formation of ni-trous gases, H3PO4, H4P2O6, very small amt. of H3PO3 and in pptn. of Cu and Cu-phospide;;
air in neat (no solvent)
passing 120 litre humid air over white P in 6 d at ambient temp., 1percent of the P are converted into H3PO2, 15-21percent into H3PO3, 72-77percent into H3PO4 and6-8percent into H4P2O6;;
Corne, I.
Journal de Pharmacie et de Chimie, 1882 , vol. 6, p. 123 - 124
Show Details
Corne, I.
Jahresber. physik. Ver. Frankfurt a. M., 1882 , p. 246
Show Details
Gmelin Handbook: P: MVol.B, 3.5.4, page 323 - 329