water in water
byproducts: CH3CO2H; on immersing a rod of white P into 0.1n Ag-acetate soln., first formation of an Ag3P-layer on P, then pptn. of Ag; mechanism discussed;;
参考文献
Walker, O. J.
Journal of the Chemical Society, 1926 , p. 1370 - 1381
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Gmelin Handbook: Ag: MVol.B5, 2.3.5.2, page 139 - 140
Plaats, J. D. van der
Recueil des Travaux Chimiques des Pays-Bas, 1885 , vol. 4, p. 87 - 89
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Gmelin Handbook: P: MVol.B, 3.5.4, page 323 - 329
iodine; potassium iodide in water; paraffin
byproducts: HI; with I2 soln. in KI;
参考文献
Vieboeck, F.
Archiv der Pharmazie (Weinheim, Germany), 1934 , vol. 272, p. 88 - 100
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Gmelin Handbook: P: MVol.B, 3.4.1.6, page 282 - 285
in neat (no solvent)
boiling pieces of P4 with 16 fold amount HNO3 (addition of Br2, HBr or I2 accelerates oxidation of P4), liquid is concentrated with addition of HNO3 (to oxidize H3PO3) in Pt crucible until white vapor of HPO3 appears;; mixture is diluted with H2O and H2S is passed into soln. to remove As and Pt, decomposition of HPO3 and H4P2O7 via heating;;
参考文献
Abbott, G. A.; Bray, W. C.
Journal of the American Chemical Society, 1909 , vol. 31, p. 729 - 763
copper(II) nitrate in not given
byproducts: Cu, Cu-phosphide; addition of white P into a warm Cu(NO3)2-soln. yields in formation of nitrous gases, H3PO3, H3PO4 and H4P2O6 and in pptn. of Cu and Cu-phos- pide; mechanism given;;
参考文献
Tauchert, F.
Z. Anorg. Chem., 1913 , vol. 79, p. 350 - 354
water
byproducts: I2; in acidic condition, explosive react.;
参考文献
Buehrer, T. F.; Schupp, O. E.
Journal of the American Chemical Society, 1927 , vol. 49, p. 9 - 15
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Gmelin Handbook: P: MVol.B, 3.5.2, page 319 - 321
