Cu(II)-sulfate or -formate or -phosphate or -hypo-; phosphate or CuO or Cu2Cl2 in not given
byproducts: Cu, Cu-phosphide; addition of white P into a warm Cu(II)-soln. yields in formation of ni-trous gases, H3PO4, H4P2O6, very small amt. of H3PO3 and in pptn. of Cu and Cu-phospide;;
参考文献
Tauchert, F.
Z. Anorg. Chem., 1913 , vol. 79, p. 350 - 354
phosphoric acid in water
at 30-35°C; concn. of H3PO4=12g/l P2O5;
参考文献
Pedler, A.
Journal of the Chemical Society, 1890 , vol. 47, p. 599 - 613
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Gmelin Handbook: P: MVol.B, 3.4.1.5, page 276 - 281
air in water
byproducts: ozone; at 15-20°C, with wet air;
参考文献
Schoenbein, C. F.
Journal fuer Praktische Chemie (Leipzig), 1846 , vol. 38, p. 81 - 91
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Gmelin Handbook: P: MVol.B, 3.5.4, page 323 - 329
water in water
byproducts: CH3CO2H; on immersing a rod of white P into 0.1n Ag-acetate soln., first formation of an Ag3P-layer on P, then pptn. of Ag; mechanism discussed;;
参考文献
Walker, O. J.
Journal of the Chemical Society, 1926 , p. 1370 - 1381
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Gmelin Handbook: Ag: MVol.B5, 2.3.5.2, page 139 - 140
Plaats, J. D. van der
Recueil des Travaux Chimiques des Pays-Bas, 1885 , vol. 4, p. 87 - 89
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Gmelin Handbook: P: MVol.B, 3.5.4, page 323 - 329
air in neat (no solvent)
passing 120 litre humid air over white P in 6 d at ambient temp., 1percent of the P are converted into H3PO2, 15-21percent into H3PO3, 72-77percent into H3PO4 and6-8percent into H4P2O6;;
参考文献
Milobedzki, T.; Makulec, M.
Roczniki Chemii, 1949 , vol. 23, p. 13 - 18
Corne, I.
Journal de Pharmacie et de Chimie, 1882 , vol. 6, p. 123 - 124
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Corne, I.
Jahresber. physik. Ver. Frankfurt a. M., 1882 , p. 246
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Gmelin Handbook: P: MVol.B, 3.5.4, page 323 - 329
