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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
121882-41-5
合成路线
（共 10 条）
764-01-2
2-丁炔-1-醇
+
813-19-4
六正丁基二锡
→
反应条件
121882-41-5
反应条件
1: 1,1,1,2,2,2-hexabutyl-distannane With n-butyllithium; copper (I) cyanide in tetrahydrofuran; hexane T=-78 - -40°C; 0.583333 h; Inert atmosphere; 2: 1-hydroxybut-2-yne in tetrahydrofuran; methanol; hexane T=-78 - -10°C; Inert atmosphere;
参考文献
Bartholomaeus, Ruben; Dommershausen, Fabian; Thiele, Markus; Karanjule, Narayan S.; Harms, Klaus; Koert, Ulrich
Chemistry - A European Journal, 2013 , vol. 19, # 23 p. 7423 - 7436
764-01-2
2-丁炔-1-醇
+
688-73-3
三正丁基氢化锡
→
反应条件
121882-41-5
反应条件
1: tri-n-butyl-tin hydride With n-butyllithium; copper (I) cyanide in tetrahydrofuran; hexane T=-78 - -40°C; 2: 1-hydroxybut-2-yne in tetrahydrofuran; hexane T=-78 - -40°C; 11 h;
参考文献
Zurwerra, Didier; Glaus, Florian; Betschart, Leo; Schuster, Julia; Gertsch, Juerg; Ganci, Walter; Altmann, Karl-Heinz
Chemistry - A European Journal, 2012 , vol. 18, # 52 p. 16868 - 16883
764-01-2
2-丁炔-1-醇
+
688-73-3
三正丁基氢化锡
→
反应条件
反应条件
tetrakis(triphenylphosphine) palladium(0) in benzene hydrostannylation, at room temperature, mixture was stood for 10 minutes; removal of solvent (vacuo), flash chromy. (silica gel, dichloromethane);
参考文献
Miyake, Hideyoshi; Yamamura, Kimiaki
Chemistry Letters, 1989 , p. 981 - 984
→
反应条件
121882-41-5
反应条件
in tetrahydrofuran; methanol -78°C to -10°C; according to Betzer et al. J. Org. Chem., 1997, 62, 7768;
参考文献
Uenishi; Kawahama; Yonemitsu; Wada; Ito
Angewandte Chemie - International Edition in English, 1998 , vol. 37, # 3 p. 320 - 323
121882-41-5
→
反应条件
256518-22-6
反应条件
manganese(IV) oxide in dichloromethane
参考文献
Studiengesellschaft Kohle MbH
Patent: US2010/56616 A1, 2010 ;
Location in patent: Sheet 6 ;
121882-41-5
+
303779-99-9
→
反应条件
3917-39-3
4-(1,4-二甲基-1-乙基)戊基酚
反应条件
triphenyl-arsane; tris(dibenzylideneacetone)dipalladium(0) chloroform complex in N,N-dimethyl-formamide T=20°C; Stille coupling; 2 h;
参考文献
Wada, Akimori; Fukunaga, Kouki; Ito, Masayoshi; Mizuguchi, Yukari; Nakagawa, Kimie; Okano, Toshio
Bioorganic and Medicinal Chemistry, 2004 , vol. 12, # 14 p. 3931 - 3942
121882-41-5
+
475673-41-7
→
反应条件
3917-39-3
4-(1,4-二甲基-1-乙基)戊基酚
反应条件
triphenyl-arsane; tris(dibenzylideneacetone)dipalladium(0) chloroform complex in N,N-dimethyl-formamide T=20°C; Stille coupling reaction; 2 h;
参考文献
Wada, Akimori; Ieki, Yasuhiro; Nakamura, Saeko; Ito, Masayoshi
Synthesis, 2005 , # 10 art. no. F00105SS, p. 1581 - 1588
121882-41-5
→
反应条件
37428-58-3
(E)-3-碘-2-丁烯-1-醇
反应条件
iodine; sodium carbonate in dichloromethane T=0°C; 0.166667 h;
参考文献
Murakami, Yusuke; Nakano, Masayuki; Shimofusa, Takuya; Furuichi, Noriyuki; Katsumura, Shigeo
Organic and Biomolecular Chemistry, 2005 , vol. 3, # 8 p. 1372 - 1374
31930-36-6
顺式-3-碘丙烯酸乙酯
+
121882-41-5
→
反应条件
86459-95-2
反应条件
dichloro bis(acetonitrile) palladium(II) in N,N-dimethyl-formamide Stille coupling;
参考文献
Clarke, Paul A.; Davie, Rebecca L.; Peace, Simon
Tetrahedron, 2005 , vol. 61, # 9 p. 2335 - 2351
→
反应条件
86459-95-2
反应条件
dichloro bis(acetonitrile) palladium(II) in N,N-dimethyl-formamide
参考文献
Clarke, Paul A.; Davie, Rebecca L.; Peace, Simon
Tetrahedron Letters, 2002 , vol. 43, # 15 p. 2753 - 2756
