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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
121994-56-7
合成路线
（共 29 条）
388120-48-7
→
反应条件
121994-56-7
反应条件
sulfuric acid in methanol
参考文献
Stahl; Kissau; Mazitschek; Huwe; Furet; Giannis; Waldmann
Journal of the American Chemical Society, 2001 , vol. 123, # 47 p. 11586 - 11593
124-41-4
甲醇钠
+
409346-50-5
→
反应条件
121994-56-7
反应条件
in methanol T=-20 - 50°C;
参考文献
Ling, Taotao; Poupon, Erwan; Rueden, Erik J.; Kim, Sun H.; Theodorakis, Emmanuel A.
Journal of the American Chemical Society, 2002 , vol. 124, # 41 p. 12261 - 12267
213026-18-7
→
反应条件
71678-03-0
3-[(十氢-1β,2β,4aβ-三甲基-5-亚甲基-1-萘基)甲基]-2-羟基-5-甲氧基苯醌
+
121994-56-7
+
388120-48-7
反应条件
argentic oxide; nitric acid in 1,4-dioxane T=20°C;
参考文献
Stahl; Kissau; Mazitschek; Huwe; Furet; Giannis; Waldmann
Journal of the American Chemical Society, 2001 , vol. 123, # 47 p. 11586 - 11593
26742-33-6
→
反应条件
121994-56-7
反应条件
1.1: Li; NH3 / tetrahydrofuran; H2O / 0.75 h / -78 - -33 °C 1.2: 76 percent / tetrahydrofuran; H2O / 2 h / Heating 2.1: 98 percent / KOtBu / toluene / 4 h / Heating 3.1: 100 percent / HCl / tetrahydrofuran / 12 h / 20 °C 4.1: 89 percent / H2; Et3N / 10percent Pd/C / methanol / 12 h / 20 °C 5.1: 98 percent / KOtBu / toluene / 3 h / Heating 6.1: 26 percent / AgO; HNO3 / dioxane / 20 °C View Scheme
参考文献
Poigny, Stephane; Guyot, Michele; Samedi, Mohammad
Journal of Organic Chemistry, 1998 , vol. 63, # 17 p. 5890 - 5894
2441-46-5
1,2,4,5-四甲氧基苯
→
反应条件
121994-56-7
反应条件
1.1: 74 percent / HBr; AcOH / 16 h / 20 °C 2.1: Li; NH3 / tetrahydrofuran; H2O / 0.75 h / -78 - -33 °C 2.2: 76 percent / tetrahydrofuran; H2O / 2 h / Heating 3.1: 98 percent / KOtBu / toluene / 4 h / Heating 4.1: 100 percent / HCl / tetrahydrofuran / 12 h / 20 °C 5.1: 89 percent / H2; Et3N / 10percent Pd/C / methanol / 12 h / 20 °C 6.1: 98 percent / KOtBu / toluene / 3 h / Heating 7.1: 26 percent / AgO; HNO3 / dioxane / 20 °C View Scheme
参考文献
Poigny, Stephane; Guyot, Michele; Samedi, Mohammad
Journal of Organic Chemistry, 1998 , vol. 63, # 17 p. 5890 - 5894
41722-49-0
(S)-5,8alpha-二甲基-3,4,8,8alpha-四氢-2H,7H-萘-1,6-二酮
→
反应条件
121994-56-7
反应条件
1.1: 87 percent / ethyl-2-methyl-1,3-dioxolan; p-TsOH / CH2Cl2 / 48 h / 20 °C 2.1: Li; NH3 / tetrahydrofuran; H2O / 0.75 h / -78 - -33 °C 2.2: 76 percent / tetrahydrofuran; H2O / 2 h / Heating 3.1: 98 percent / KOtBu / toluene / 4 h / Heating 4.1: 100 percent / HCl / tetrahydrofuran / 12 h / 20 °C 5.1: 89 percent / H2; Et3N / 10percent Pd/C / methanol / 12 h / 20 °C 6.1: 98 percent / KOtBu / toluene / 3 h / Heating 7.1: 26 percent / AgO; HNO3 / dioxane / 20 °C View Scheme
参考文献
Poigny, Stephane; Guyot, Michele; Samedi, Mohammad
Journal of Organic Chemistry, 1998 , vol. 63, # 17 p. 5890 - 5894
86489-89-6
3-(溴甲基)-1,2,4,5-四甲氧基苯
→
反应条件
121994-56-7
反应条件
1.1: Li; NH3 / tetrahydrofuran; H2O / 0.75 h / -78 - -33 °C 1.2: 76 percent / tetrahydrofuran; H2O / 2 h / Heating 2.1: 98 percent / KOtBu / toluene / 4 h / Heating 3.1: 100 percent / HCl / tetrahydrofuran / 12 h / 20 °C 4.1: 89 percent / H2; Et3N / 10percent Pd/C / methanol / 12 h / 20 °C 5.1: 98 percent / KOtBu / toluene / 3 h / Heating 6.1: 26 percent / AgO; HNO3 / dioxane / 20 °C View Scheme
参考文献
Poigny, Stephane; Guyot, Michele; Samedi, Mohammad
Journal of Organic Chemistry, 1998 , vol. 63, # 17 p. 5890 - 5894
213026-14-3
→
反应条件
121994-56-7
反应条件
1: 98 percent / KOtBu / toluene / 4 h / Heating 2: 100 percent / HCl / tetrahydrofuran / 12 h / 20 °C 3: 89 percent / H2; Et3N / 10percent Pd/C / methanol / 12 h / 20 °C 4: 98 percent / KOtBu / toluene / 3 h / Heating 5: 26 percent / AgO; HNO3 / dioxane / 20 °C View Scheme
参考文献
Poigny, Stephane; Guyot, Michele; Samedi, Mohammad
Journal of Organic Chemistry, 1998 , vol. 63, # 17 p. 5890 - 5894
213026-15-4
→
反应条件
121994-56-7
反应条件
1: 100 percent / HCl / tetrahydrofuran / 12 h / 20 °C 2: 89 percent / H2; Et3N / 10percent Pd/C / methanol / 12 h / 20 °C 3: 98 percent / KOtBu / toluene / 3 h / Heating 4: 26 percent / AgO; HNO3 / dioxane / 20 °C View Scheme
参考文献
Poigny, Stephane; Guyot, Michele; Samedi, Mohammad
Journal of Organic Chemistry, 1998 , vol. 63, # 17 p. 5890 - 5894
583-63-1
2-苯醌
→
反应条件
121994-56-7
反应条件
1.1: methanol / 20 - 22 °C 2.1: PbO2 / 20 - 22 °C 3.1: 96 percent / H2SO4 / methanol 4.1: 5.50 mg / NaBH4 / ethanol / 3 h / 0 °C 5.1: 4.9 mg / NaOH; NaHSO3 / ethanol / 4 h / 70 - 80 °C 6.1: 74 percent / HBr; AcOH / 16 h / 20 °C 7.1: Li; NH3 / tetrahydrofuran; H2O / 0.75 h / -78 - -33 °C 7.2: 76 percent / tetrahydrofuran; H2O / 2 h / Heating 8.1: 98 percent / KOtBu / toluene / 4 h / Heating 9.1: 100 percent / HCl / tetrahydrofuran / 12 h / 20 °C 10.1: 89 percent / H2; Et3N / 10percent Pd/C / methanol / 12 h / 20 °C 11.1: 98 percent / KOtBu / toluene / 3 h / Heating 12.1: 26 percent / AgO; HNO3 / dioxane / 20 °C View Scheme
参考文献
Stahl; Kissau; Mazitschek; Huwe; Furet; Giannis; Waldmann
Journal of the American Chemical Society, 2001 , vol. 123, # 47 p. 11586 - 11593
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