in tetrahydrofuran -78 deg C to room temp. then room temp., 30 min;
参考文献
Heras, Maria A. de las; Molina, Andres; Vaquero, Juan J.; Navio, Jose L. Garcia; Alvarez-Builla, Julio
Journal of Organic Chemistry, 1993 , vol. 58, # 21 p. 5862 - 5865
methylmagnesium bromide in diethyl ether addn. of CH3MgBr to Fe-complex in diethylether under N2 at -78°C, stirring at -78°C for 7 h, addn. of tert.-BuBr to the dark green mixture at -78°C, allowing to warm to room temp.; filtration, removal of solvent under reduced pressure, sepn. of products by column chromy. (SiO2, light petroleum-diethy ether, 2:1);
参考文献
Danks, Timothy N.; Rakshit, Devajyoti; Thomas, Susan E.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1988 , p. 2091 - 2094
