1,3-二(4-甲氧苯基)-1,1,3,3-四甲基二硅氧烷合成路线 （共 21 条）
反应条件
1: (4-MeOC6H4)Me2SiH With dirhodium tetraacetate; potassium carbonate in acetonitrile Schlenk techniqueInert atmosphere; 2: carbon dioxide in acetonitrile T=50°C; 2 h; Schlenk technique;
参考文献
Itagaki, Shintaro; Yamaguchi, Kazuya; Mizuno, Noritaka
Journal of Molecular Catalysis A: Chemical, 2013 , vol. 366, p. 347 - 352
反应条件
(TBA)4[γ-SiW10O34(H2O)2]; dihydrogen peroxide in water; acetonitrile T=59.84°C; 4 h;
参考文献
Mitsudome, Takato; Noujima, Akifumi; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi
Chemical Communications, 2009 , # 35 p. 5302 - 5304
反应条件
1: 1-bromo-4-methoxy-benzene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 0.5 h; Inert atmosphere; 2: 1,3-dichloro-1,1,3,3-tetramethyldisiloxane in tetrahydrofuran; hexane T=-78 - 20°C; Inert atmosphere;
参考文献
Boehner, Christine M.; Frye, Elizabeth C.; O'Connell, Kieron M. G.; Galloway, Warren R. J. D.; Sore, Hannah F.; Dominguez, Patricia Garcia; Norton, David; Hulcoop, David G.; Owen, Martin; Turner, Gillian; Crawford, Claire; Horsley, Helen; Spring, David R.
Chemistry - A European Journal, 2011 , vol. 17, # 47 p. 13230 - 13239
反应条件
Pd0(tris(tert-butyl)phosphine)2; N-ethyl-N,N-diisopropylamine in tetrahydrofuran T=20°C; 4 h;
参考文献
Kurihara, Yu; Yamanoi, Yoshinori; Nishihara, Hiroshi
Chemical Communications, 2013 , vol. 49, # 96 p. 11275 - 11277
反应条件
9,10-anthracenedicarbonitrile; oxygen in acetonitrile 3 h; Ambient temperatureIrradiation;
参考文献
Mizuno, Kazuhiko; Tamai, Toshiyuki; Hashida, Isao; Otsuji, Yoshio
Journal of Organic Chemistry, 1995 , vol. 60, # 9 p. 2935 - 2937
反应条件
lithium in tetrahydrofuran T=0°C; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Rahman, Noorsaadah Abd.; Fleming, Ian; Zwicky, Anna B.
Journal of Chemical Research, Miniprint, 1992 , # 9 p. 2401 - 2408
反应条件
9,10-anthracenedicarbonitrile; oxygen in acetonitrile 3 h; Ambient temperatureIrradiation; Rate constantMechanism;
参考文献
Mizuno, Kazuhiko; Tamai, Toshiyuki; Hashida, Isao; Otsuji, Yoshio
Journal of Organic Chemistry, 1995 , vol. 60, # 9 p. 2935 - 2937
反应条件
1: 1.) Mg / 1.) ether, 2.) ether, RT, 30 min 2: KHF2 / 0.5 h / Heating 3: 1.) BuLi / 1.) hexane, THF, Et2O, n-pentane, -110 deg C, 2 h, 2.) hexane, THF, Et2O, n-pentane, a) -110 deg C, 30 min, b) -110 deg C - RT, overnight View Scheme
参考文献
Eaborn, Colin; Jones, Karen L.; Lickiss, Paul D.
Journal of Organometallic Chemistry, 1994 , vol. 466, # 1-2 p. 35 - 42
反应条件
1: KHF2 / 0.5 h / Heating 2: 1.) BuLi / 1.) hexane, THF, Et2O, n-pentane, -110 deg C, 2 h, 2.) hexane, THF, Et2O, n-pentane, a) -110 deg C, 30 min, b) -110 deg C - RT, overnight View Scheme
参考文献
Eaborn, Colin; Jones, Karen L.; Lickiss, Paul D.
Journal of Organometallic Chemistry, 1994 , vol. 466, # 1-2 p. 35 - 42
反应条件
n-butyllithium; bis(trimethylsilyl)dichloromethane 1.) hexane, THF, Et2O, n-pentane, -110 deg C, 2 h, 2.) hexane, THF, Et2O, n-pentane, a) -110 deg C, 30 min, b) -110 deg C - RT, overnight; Multistep reaction. Title compound not separated from byproducts;
参考文献
Eaborn, Colin; Jones, Karen L.; Lickiss, Paul D.
Journal of Organometallic Chemistry, 1994 , vol. 466, # 1-2 p. 35 - 42
