5β-雄烷-3,17-二酮合成路线 （共 14 条）
反应条件
benzeneselenenyl chloride; dihydrogen peroxide Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Abul-Hajj, Yusuf J.
Journal of the Chemical Society, Chemical Communications, 1985 , # 21 p. 1479 - 1481
反应条件
hydrogen; (dimethyl)(phenyl)phosphine; tert-butyl alcohol; [{(Ph3P)CuH}6] in benzene T=20°C; Catalytic hydrogenation; P=760 Torr; 30 h;
参考文献
Tetrahedron, , vol. 56, # 18 p. 2789 - 2798
反应条件
BH3·NMe3; silica gel; iron(III) chloride in benzene 2 h; Ambient temperature;
参考文献
Chemistry Letters, , p. 61 - 64
反应条件
methanol; sodium tetrahydroborate
参考文献
Elisberg et al.
Journal of the American Chemical Society, 1952 , vol. 74, p. 2814
反应条件
potassium tri-sec-butyl-borohydride in tetrahydrofuran T=22°C; 25 h; var. time, temp., amount of reagent; Product distribution;
参考文献
Journal of the Chemical Society, Chemical Communications, , # 21 p. 1239 - 1240
反应条件
potassium phosphate buffer; NADPH; recombinant cDNA-expressed aldo-keto reductase (AKR1C12) T=25°C; Enzyme kinetics;
参考文献
Endo, Satoshi; Matsumoto, Kengo; Matsunaga, Toshiyuki; Ishikura, Shuhei; Tajima, Kazuo; El-Kabbani, Ossama; Hara, Akira
Biological and Pharmaceutical Bulletin, 2006 , vol. 29, # 12 p. 2488 - 2492
反应条件
504 h; Rhodotorula mucilaginosa;
参考文献
Bulletin de l'Academie Polonaise des Sciences, Serie des Sciences Chimiques, , vol. 30, # 1-12 p. 13 - 21
反应条件
1: Na / methanol / 1 h / 20 °C 2: 467 mg / Zn; glacial acetic acid / 0.17 h View Scheme
参考文献
Steroids, , vol. 67, # 3-4 p. 311 - 319
反应条件
hydrogen; (dimethyl)(phenyl)phosphine; tert-butyl alcohol; [{(Ph3P)CuH}6] in benzene T=20°C; Catalytic hydrogenation; P=760 Torr; 30 h;
参考文献
Tetrahedron, , vol. 56, # 18 p. 2789 - 2798
反应条件
BH3·NMe3; silica gel; iron(III) chloride in benzene 2 h; Ambient temperature;
参考文献
Chemistry Letters, , p. 61 - 64
