1: bromobenzene With magnesium in tetrahydrofuran 2: crotonaldehyde in tetrahydrofuran T=0°C; Grignard reaction; 3: With water in tetrahydrofuran
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Journal of the American Chemical Society, 2008 , vol. 130, # 41 p. 13608 - 13617
1: With chloro-trimethyl-silane; copper(I) thiophene-2-carboxylate; (R)-p-tol-BINAP in diethyl ether T=-78°C; Inert atmosphere; 2: With hydrogenchloride in methanol; diethyl ether; water Inert atmosphere; optical yield given as percent eeenantiospecific reaction;
Provencher, Brian A.; Bartelson, Keith J.; Liu, Yan; Foxman, Bruce M.; Deng, Li
Angewandte Chemie - International Edition, 2011 , vol. 50, # 45 p. 10565 - 10569
