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citrate buffer; pyruvate decarboxylase; thiamine diphosphate; magnesium chloride in ethylene glycol T=25°C; var. pH and times; Rate constantMechanism;

citrate buffer; pyruvate decarboxylase; thiamine diphosphate; magnesium chloride in ethylene glycol T=25°C; var. pH and times; Rate constantMechanism;

phospho-tungstic acid; phosphotungstic acid in toluene 8 h; Heating;

1: 2.) NaOH / 1.) water, reflux, 5 min, room temp.,2 h; 2.) reflux, 15 min 2: 75 percent / phosphorus pentasulfide / pyridine / 6 h / Heating 3: 1.) sodium methoxide; / 1.) methanol; 2.) room temp., overnight View Scheme

1: 2.) NaOH / 1.) water, reflux, 5 min, room temp.,2 h; 2.) reflux, 15 min 2: 75 percent / phosphorus pentasulfide / pyridine / 6 h / Heating View Scheme

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '11342937', constants.ctx, '0')">potassium hydroxide</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '1098229', constants.ctx, '0')">methanol</a> <br />6&nbsp;h;&nbsp;<br /> &nbsp;

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '1098214', constants.ctx, '0')">hydrogenchloride</a>;&nbsp;<a href="#" onclick="return RXDsubstances(event, this, '11342940', constants.ctx, '0')">sodium hydroxide</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '1718733', constants.ctx, '0')">ethanol</a> <br />0.25&nbsp;h;&nbsp;<br /> &nbsp;