1: With bis(1-neomenthylindenyl)ZrCl2 in benzene
T=22°C; 24 h; Inert atmosphereSchlenk technique;
2: With oxygen in benzene
T=0°C; 26 h;
3: With hydrogenchloride; water in benzene
T=0°C; enantioselective reaction;
参考文献
Parfenova, Lyudmila V.; Kovyazin, Pavel V.; Tyumkina, Tatyana V.; Berestova, Tatyana V.; Khalilov, Leonard M.; Dzhemilev, Usein M.
Journal of Organometallic Chemistry, 2013 , vol. 723, p. 19 - 25
Khalilov, Leonard M.; Parfenova, Ludmila V.; Pechatkina, Svetlana V.; Ibragimov, Askhat G.; Genet, Jean P.; Dzhemilev, Usein M.; Beletskaya, Irina P.
Journal of Organometallic Chemistry, 2004 , vol. 689, # 2 p. 444 - 453
aluminium trichloride in neat (no solvent)
byproducts: NaCl; under N2 or Ar; mixt. of (AlH3)(n), Na(i-Bu)2AlH2 and olefin (molar ratio 1:0.20:5) heated in ball mill to 100°C; stored at 90-100°C for 1.5 h; balls sepd.; filtered; excess olefin removed in vac.; AlCl3 added; heated with stirring at 80-90°C for 1.5 h; filtered; elem. anal.;
参考文献
Gavrilenko
Russian Chemical Bulletin, 2003 , vol. 52, # 5 p. 1161 - 1163
