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乙二醇
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63148-62-9
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二甲基亚砜
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
癸烷
合成路线
(共 500 条)
124-18-5
癸烷
→
反应条件
1565-81-7
3-正癸醇
+
1120-06-5
2-癸醇
+
5205-34-5
5-癸醇
+
112-30-1
1-癸醇
+
2051-31-2
4-正癸醇
反应条件
iodosylbenzene; MnTTPPP(OAc) in benzene T=25°C; 7 h; other catalysts and regioselectivity investigated; Mechanism;
参考文献
Cook, Bruce R.; Reinert, Thomas J.; Suslick, Kenneth S.
Journal of the American Chemical Society, 1986 , vol. 108, # 23 p. 7281 - 7286
124-18-5
癸烷
→
反应条件
1565-81-7
3-正癸醇
反应条件
potassium dihydrogenphosphate; magnesium sulphate heptahydrate; air; D-glucose in water T=25°C; pH=6.0; 216 h; Microbiological reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Oda, Shinobu; Isshiki, Kunio; Ohashi, Shinichi
Bulletin of the Chemical Society of Japan, 2009 , vol. 82, # 1 p. 105 - 109
124-18-5
癸烷
→
反应条件
1565-81-7
3-正癸醇
+
1120-06-5
2-癸醇
+
112-30-1
1-癸醇
+
2051-31-2
4-正癸醇
反应条件
iron sulphate heptahydrate; mangabese(II) sulphate pentahydrate; air; D-glucose; calcium chloride in water T=25°C; pH=6.0; 168 h; Microbiological reaction; regioselective reaction;
参考文献
Oda, Shinobu; Isshiki, Kunio; Ohashi, Shinichi
Bulletin of the Chemical Society of Japan, 2009 , vol. 82, # 1 p. 105 - 109
124-18-5
癸烷
→
反应条件
1565-81-7
3-正癸醇
+
693-54-9
甲基辛基甲酮
+
820-29-1
5-癸酮
+
928-80-3
3-癸酮
反应条件
tert.-butylhydroperoxide; tris(triphenylphosphine)ruthenium(II) chloride in benzene T=20°C; 1.5 h; Product distribution; Further Variations:Catalysts;
参考文献
Murahashi; Komiya; Oda; Kuwabara; Naota
Journal of Organic Chemistry, 2000 , vol. 65, # 26 p. 9186 - 9193
124-18-5
癸烷
→
反应条件
1565-81-7
3-正癸醇
+
1120-06-5
2-癸醇
+
5205-34-5
5-癸醇
+
693-54-9
甲基辛基甲酮
+
928-80-3
3-癸酮
+
2051-31-2
4-正癸醇
反应条件
iron sulphate heptahydrate; mangabese(II) sulphate pentahydrate; air; D-glucose; calcium chloride in water T=25°C; pH=6.0; 168 h; Microbiological reaction; regioselective reaction;
参考文献
Oda, Shinobu; Isshiki, Kunio; Ohashi, Shinichi
Bulletin of the Chemical Society of Japan, 2009 , vol. 82, # 1 p. 105 - 109
124-18-5
癸烷
→
反应条件
1565-81-7
3-正癸醇
+
1120-06-5
2-癸醇
+
5205-34-5
5-癸醇
+
820-29-1
5-癸酮
+
624-16-8
4-癸酮
+
2051-31-2
4-正癸醇
反应条件
iron sulphate heptahydrate; mangabese(II) sulphate pentahydrate; air; D-glucose; calcium chloride in water T=25°C; pH=6.0; 168 h; Microbiological reaction; regioselective reaction;
参考文献
Oda, Shinobu; Isshiki, Kunio; Ohashi, Shinichi
Bulletin of the Chemical Society of Japan, 2009 , vol. 82, # 1 p. 105 - 109
124-18-5
癸烷
→
反应条件
1565-81-7
3-正癸醇
+
5205-34-5
5-癸醇
+
112-30-1
1-癸醇
+
820-29-1
5-癸酮
+
624-16-8
4-癸酮
+
2051-31-2
4-正癸醇
反应条件
iron sulphate heptahydrate; mangabese(II) sulphate pentahydrate; air; D-glucose; calcium chloride in water T=25°C; pH=6.0; 168 h; Microbiological reaction; regioselective reaction;
参考文献
Oda, Shinobu; Isshiki, Kunio; Ohashi, Shinichi
Bulletin of the Chemical Society of Japan, 2009 , vol. 82, # 1 p. 105 - 109
124-18-5
癸烷
→
反应条件
1565-81-7
3-正癸醇
+
5205-34-5
5-癸醇
+
693-54-9
甲基辛基甲酮
+
624-16-8
4-癸酮
+
928-80-3
3-癸酮
+
2051-31-2
4-正癸醇
反应条件
iron sulphate heptahydrate; mangabese(II) sulphate pentahydrate; air; D-glucose; calcium chloride in water T=25°C; pH=6.0; 168 h; Microbiological reaction; regioselective reaction;
参考文献
Oda, Shinobu; Isshiki, Kunio; Ohashi, Shinichi
Bulletin of the Chemical Society of Japan, 2009 , vol. 82, # 1 p. 105 - 109
124-18-5
癸烷
→
反应条件
1565-81-7
3-正癸醇
+
1120-06-5
2-癸醇
+
5205-34-5
5-癸醇
+
112-30-1
1-癸醇
+
820-29-1
5-癸酮
+
624-16-8
4-癸酮
+
2051-31-2
4-正癸醇
反应条件
iron sulphate heptahydrate; mangabese(II) sulphate pentahydrate; air; D-glucose; calcium chloride in water T=25°C; pH=6.0; 168 h; Microbiological reaction; regioselective reaction;
参考文献
Oda, Shinobu; Isshiki, Kunio; Ohashi, Shinichi
Bulletin of the Chemical Society of Japan, 2009 , vol. 82, # 1 p. 105 - 109
124-18-5
癸烷
→
反应条件
1565-81-7
3-正癸醇
+
1120-06-5
2-癸醇
+
5205-34-5
5-癸醇
+
112-30-1
1-癸醇
+
693-54-9
甲基辛基甲酮
+
820-29-1
5-癸酮
+
624-16-8
4-癸酮
+
928-80-3
3-癸酮
+
2051-31-2
4-正癸醇
反应条件
iron sulphate heptahydrate; mangabese(II) sulphate pentahydrate; air; D-glucose; calcium chloride in water T=25°C; pH=6.0; 168 h; Microbiological reaction; regioselective reaction;
参考文献
Oda, Shinobu; Isshiki, Kunio; Ohashi, Shinichi
Bulletin of the Chemical Society of Japan, 2009 , vol. 82, # 1 p. 105 - 109
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