sodium sulfate in not given Electrolysis; NaHCO2 is formed by H in nascent state at the electrlytic redn. of CO2, dissolved under pressure in a satd. soln. of Na2SO4;;
in not given electrolysis of Na salt solns. at lead amalgam cathod; passing CO2 through formed sodium lead amalgam with vigorous stirring up to foaming;;
参考文献
Rabinowitsch, M.; Maschowetz, A.
Zeitschrift fuer Elektrochemie, 1930 , vol. 36, p. 846 - 850
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Gmelin Handbook: Na: SVol.4, 14, page 1398 - 1400
in methanol T=20°C; P=30400 Torr; electrolysis by using Cu working electrode, Pt counter electrode, Ag quasi-reference electrode, electrolyte: tetrabutylammonium tetrafluoroborate, current density: 200 mA cm-2;
参考文献
Saeki; Hashimoto; Fujishima; Kimura; Omata
Journal of physical chemistry, 1995 , vol. 99, # 20 p. 8440 - 8446
in methanol T=20°C; P=30400 Torr; electrolysis by using Cu working electrode, Pt counter electrode, Ag quasi-reference electrode, electrolyte: tetrabutylammonium tetrafluoroborate, current density: 200 mA cm-2;
参考文献
Saeki; Hashimoto; Fujishima; Kimura; Omata
Journal of physical chemistry, 1995 , vol. 99, # 20 p. 8440 - 8446
Chadwick, Derek J.; Hodgson, Simon T.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982 , # 8 p. 1833 - 1836
