2,4-二氯-6-(苯基甲氧基)-苯丙醛合成路线 （共 2 条）
反应条件
1: K2CO3 / acetone / 4 h / Heating 2: 97 percent / N,N-diethylaniline / 12 h / Heating 3: 79 percent / K2CO3 / dimethylformamide / 8 h / Heating 4: 1.) borane-THF complex, 2.) 3M aq. NaOH, 30percent v/v H2O2 / 1.) THF, 6 deg C -> room temperature, 2 h, 2.) H2O, 50 deg C, 1 h 5: 98 percent / pyridinium chlorochromate, sodium acetate / CH2Cl2 / 1.) 10 deg C, 1 h, 2.) room temperature, 1 h View Scheme
参考文献
Ashton, Michael J.; Hills, Susan J.; Newton, Christopher G.; Taylor, John B.; Tondu, Sylvie C. D.
Heterocycles, 1989 , vol. 28, # 2 p. 1015 - 1035
反应条件
1: 79 percent / K2CO3 / dimethylformamide / 8 h / Heating 2: 1.) borane-THF complex, 2.) 3M aq. NaOH, 30percent v/v H2O2 / 1.) THF, 6 deg C -> room temperature, 2 h, 2.) H2O, 50 deg C, 1 h 3: 98 percent / pyridinium chlorochromate, sodium acetate / CH2Cl2 / 1.) 10 deg C, 1 h, 2.) room temperature, 1 h View Scheme
参考文献
Ashton, Michael J.; Hills, Susan J.; Newton, Christopher G.; Taylor, John B.; Tondu, Sylvie C. D.
Heterocycles, 1989 , vol. 28, # 2 p. 1015 - 1035
