4-甲基-2-氧代-2H-苯并吡喃-7-基2-乙酰氨基-2-脱氧吡喃己糖苷合成路线 （共 11 条）
反应条件
sodium methylate in methanol 0.25 h; Ambient temperature;
参考文献
Szweda, R.; Spohr, U.; Lemieux, R. U.; Schindler, D.; Bishop, D. F.; Desnick, R. J.
Canadian Journal of Chemistry, 1989 , vol. 67, p. 1388 - 1391
反应条件
1: 33 percent / silver trifluoromethanesulfonate, sym-collidine, 4 Angstroem molecular sieves / CH2Cl2 / Ambient temperature 2: 1.) H2; / 1.) 5percent palladium-on charcoal / 1.) aq. EtOH, 2h; 2.) pyridine, 1h, room temperature 3: 90 percent / 0.5N sodium methoxide / methanol / 0.25 h / Ambient temperature View Scheme
参考文献
Canadian Journal of Chemistry, , vol. 67, p. 1388 - 1391
反应条件
1: 33 percent / silver trifluoromethanesulfonate, sym-collidine, 4 Angstroem molecular sieves / CH2Cl2 / Ambient temperature 2: 1.) H2; / 1.) 5percent palladium-on charcoal / 1.) aq. EtOH, 2h; 2.) pyridine, 1h, room temperature 3: 90 percent / 0.5N sodium methoxide / methanol / 0.25 h / Ambient temperature View Scheme
参考文献
Canadian Journal of Chemistry, , vol. 67, p. 1388 - 1391
反应条件
1: 33 percent / silver trifluoromethanesulfonate, sym-collidine, 4 Angstroem molecular sieves / CH2Cl2 / Ambient temperature 2: 1.) H2; / 1.) 5percent palladium-on charcoal / 1.) aq. EtOH, 2h; 2.) pyridine, 1h, room temperature 3: 90 percent / 0.5N sodium methoxide / methanol / 0.25 h / Ambient temperature View Scheme
参考文献
Canadian Journal of Chemistry, , vol. 67, p. 1388 - 1391
反应条件
1: 1.) H2; / 1.) 5percent palladium-on charcoal / 1.) aq. EtOH, 2h; 2.) pyridine, 1h, room temperature 2: 90 percent / 0.5N sodium methoxide / methanol / 0.25 h / Ambient temperature View Scheme
参考文献
Canadian Journal of Chemistry, , vol. 67, p. 1388 - 1391
反应条件
1: 1.) azidonitration; 2.) oxalyl chloride / 2.) CH2Cl2, DMF, 1h, 0 deg C 2: 33 percent / silver trifluoromethanesulfonate, sym-collidine, 4 Angstroem molecular sieves / CH2Cl2 / Ambient temperature 3: 1.) H2; / 1.) 5percent palladium-on charcoal / 1.) aq. EtOH, 2h; 2.) pyridine, 1h, room temperature 4: 90 percent / 0.5N sodium methoxide / methanol / 0.25 h / Ambient temperature View Scheme
参考文献
Canadian Journal of Chemistry, , vol. 67, p. 1388 - 1391
反应条件
endo-α-N-acetylgalactosaminidase; manganese (II) chloride in water T=37°C; pH=6.8; aq. bufferEnzymatic reaction;
参考文献
Ju, Tongzhong; Xia, Baoyun; PAryal, Rajindra; Wang, Wenyi; Wang, Yingchun; Ding, Xiaokun; Mi, Rongjuan; He, Miao; Richard D. Cummings
Glycobiology, 2011 , vol. 21, # 3 p. 352 - 362
反应条件
endo-α-N-acetylgalactosaminidase; manganese (II) chloride T=37°C; pH=6.8; 1 h; aq. bufferEnzymatic reaction;
参考文献
Ju, Tongzhong; Xia, Baoyun; PAryal, Rajindra; Wang, Wenyi; Wang, Yingchun; Ding, Xiaokun; Mi, Rongjuan; He, Miao; Richard D. Cummings
Glycobiology, 2011 , vol. 21, # 3 p. 352 - 362
反应条件
manganese (II) chloride T=37°C; pH=6.8; 16 h; aq. bufferEnzymatic reaction;
参考文献
Ju, Tongzhong; Xia, Baoyun; PAryal, Rajindra; Wang, Wenyi; Wang, Yingchun; Ding, Xiaokun; Mi, Rongjuan; He, Miao; Richard D. Cummings
Glycobiology, 2011 , vol. 21, # 3 p. 352 - 362
反应条件
endo-α-N-acetylgalactosaminidase; manganese (II) chloride T=37°C; pH=6.8; 1 h; aq. bufferEnzymatic reaction;
参考文献
Ju, Tongzhong; Xia, Baoyun; PAryal, Rajindra; Wang, Wenyi; Wang, Yingchun; Ding, Xiaokun; Mi, Rongjuan; He, Miao; Richard D. Cummings
Glycobiology, 2011 , vol. 21, # 3 p. 352 - 362
