乙基-2,3,4,6-O-四苄基-Beta-D-硫代半乳糖苷合成路线 (共 2 条)
反应条件
1: bromine / CH2Cl2 / 0.25 h / 0 °C
2: 65 percent / triethylamine / tetraethylammonium bromide / CH2Cl2; dimethylformamide / 48 h / Ambient temperature
3: 60 percent / 1.) potassium tert-butoxyde, 2.) mercury(II) oxide, mercury(II) chloride / dimethylsulfoxide; acetone; H2O / 1.) methyl sulfoxide, potassium tert-butoxide, 100 deg C., 2h, 2.) mercury(II) oxide, mercury(II) chloride, aceton-water, 30 min., room temperature
4: 70 percent / molecular sieve 4 Angstroem, mercury(II) cyanide / benzene; nitromethane / 40 °C
5: hydrogen / 10percent Pd/C / methanol / 36 h / Ambient temperature
6: sodium methoxide / methanol; H2O
View Scheme
参考文献
Sarkar, Arun K.; Ray, Asim K.; Roy, Nirmolendu
Carbohydrate Research, 1989 , vol. 190, p. 181 - 190
反应条件
<b>Multi-step reaction with 2 steps<br /> </b>1: NaOMe / methanol<br />2: 6 g / NaH / dimethylformamide<br /> <br />
参考文献
Dasgupta, Falguni; Garegg, Per J. Acta Chemica Scandinavica, 1989 , vol. 43, # 5 p. 471 - 475