(1,3-苯并噻唑-2-基甲基)锂合成路线 （共 11 条）
反应条件
in tetrahydrofuran; diethyl ether under N2, addn. of soln. oftriphenylstannyliodide in THF to soln. of 2-(lithiomethyl)benzothiazole in Et2O, stirring at -78 ° C for 1 h, warming up to room temp.; evapn., residue redissolved in cyclohexane/ethyl acetate (1:3), washing with water, organic layer dried over MgSO4, major products are Ph3SnSnPh3 and 1,2-dibenzothiazolylethane;
参考文献
Journal of Organometallic Chemistry, , vol. 365, p. 61 - 74
反应条件
in diethyl ether; benzene T=-78°C; 1 h;
参考文献
Journal of Heterocyclic Chemistry, , vol. 28, # 8 p. 1933 - 1936
反应条件
in diethyl ether; benzene T=-78°C; 1 h;
参考文献
Journal of Heterocyclic Chemistry, , vol. 28, # 8 p. 1933 - 1936
反应条件
in tetrahydrofuran T=-78°C;
参考文献
Epifani, Erbana; Florio, Saverio; Troisi, Luigino
Tetrahedron, 1990 , vol. 46, p. 4031 - 4038
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Florio; Troisi
Tetrahedron Letters, 1993 , vol. 34, # 19 p. 3141 - 3144
反应条件
in diethyl ether; benzene T=-78°C; 1 h;
参考文献
Costa, Maria Virginia; Brembilla, Alain; Roizard, Denis; Lochon, Pierre
Journal of Heterocyclic Chemistry, 1991 , vol. 28, # 8 p. 1933 - 1936
反应条件
in diethyl ether 1) -78 deg C, 1 h, 2) to 0 deg C;
参考文献
Costa, Maria Virginia; Brembilla, Alain; Roizard, Denis; Lochon, Pierre
Journal of Heterocyclic Chemistry, 1991 , vol. 28, # 6 p. 1541 - 1544
反应条件
in diethyl ether
1) -78 deg C, 1 h, 2) to 0 deg C;
参考文献
Costa, Maria Virginia; Brembilla, Alain; Roizard, Denis; Lochon, Pierre
Journal of Heterocyclic Chemistry, 1991 , vol. 28, # 6 p. 1541 - 1544
参考文献
Epifani, Erbana; Florio, Saverio; Troisi, Luigino
Tetrahedron, 1990 , vol. 46, p. 4031 - 4038
反应条件
in tetrahydrofuran
T=-78 - 25°C; 6 h;
参考文献
Florio, Saverio; Troisi, Luigino; Capriati, Vito
Tetrahedron Letters, 1995 , vol. 36, # 11 p. 1913 - 1916
反应条件
in tetrahydrofuran; diethyl ether
under N2, addn. of soln. oftriphenylstannyliodide in THF to soln. of 2-(lithiomethyl)benzothiazole in Et2O, stirring at -78 ° C for 1 h, warming up to room temp.; evapn., residue redissolved in cyclohexane/ethyl acetate (1:3), washing with water, organic layer dried over MgSO4, major products are Ph3SnSnPh3 and 1,2-dibenzothiazolylethane;
参考文献
Molloy, Kieran C.; Waterfield, Philip C.; Mahon, Mary F.
Journal of Organometallic Chemistry, 1989 , vol. 365, p. 61 - 74
