in gas Electric Arc; mixtures sontaining 1 percent PCl3 and 3 percent O2 in He were subjected to pulsed electric discharge;

oxygen in gas 1200 K; identification by mass spectrometry;

in neat (no solvent, gas phase) Kinetics; byproducts: O2, ClO, Cl; further products: PO3, Cl2O, and Cl2; POCl2(1-) and O3 reacted in AFRL selected ion flow tube; rate constants and branching fractions measured at 163, 294, and 400 K at a He pressure of 0.4 Torr;

byproducts: pyridine; >450 K, 10 Pa;

T=176.9°C;

in N,N-dimethyl-formamide