5,5-二甲基-1,3-环己二酮合成路线 （共 504 条）
反应条件
2-(tert-butyl)-1,1,3,3-tetramethylguanidine in benzene
T=60°C; 24 h;
参考文献
Barton, Derek H. R.; Blazejewski, Jean-Claude; Charpiot, Brigitte; Finet, Jean-Pierre; Motherwell, William B.; et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 2667 - 2676
反应条件
1: NaOtBu
2: aq. HCl
3: NaOtBu
View Scheme
参考文献
Beringer,F.M. et al.
Tetrahedron, 1960 , vol. 8, p. 49 - 63
参考文献
Beringer,F.M. et al.
Tetrahedron, 1960 , vol. 8, p. 49 - 63
反应条件
1,4-dioxane; sodium hydroxide
参考文献
Neiland et al.
Zhurnal Obshchei Khimii, 1958 , vol. 28, p. 1201,1203; engl. Ausg. S. 1256, 1258
反应条件
2-(tert-butyl)-1,1,3,3-tetramethylguanidine; trichloroacetic acid in benzene
T=60°C; 24 h; var. pH; Product distribution;
参考文献
Barton, Derek H. R.; Blazejewski, Jean-Claude; Charpiot, Brigitte; Finet, Jean-Pierre; Motherwell, William B.; et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 2667 - 2676
反应条件
1: 95 percent / CH2Cl2 / 0.25 h / 20 °C
2: NH4Cl, 1 M aq. HCl / CH2Cl2
3: 100 percent / BF3*Et2O / diethyl ether; CH2Cl2 / 5 h
View Scheme
参考文献
Bolte, Matthew L.; Crow, Crow, Wilfrid D.; Yoshida, Shigeo
Australian Journal of Chemistry, 1982 , vol. 35, # 7 p. 1421 - 1429
反应条件
phosphorus pentoxide in acetic acid
T=120°C; 0.75 h;
参考文献
Ahluwalia, V K; Kiran, Sushma; Aggarwal, R; Arora, K K
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1991 , vol. 30, # 12 p. 1095 - 1097
反应条件
indium tribromide in 1,2-dichloro-ethane
T=80°C; 1.5 h;
参考文献
Yadav; Subba Reddy; Raghavendra Rao; Narender
Tetrahedron Letters, 2009 , vol. 50, # 27 p. 3963 - 3965
反应条件
zinc(II) chloride in n-heptane; benzene
31 h; Heating;
参考文献
Ahmed, M. G.; Ahmed, S. A.; Bahar, M. H.; Khondaker, M. A.; Islam, M. A.; Anam, A. K. M. M.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1982 , vol. 21, # 5 p. 470 - 471
反应条件
FeCl3*6H2O; 1-n-butyl-3-methylimidazolium tetrafluoroborate
T=80°C; 8 h;
参考文献
Zhang, Xinying; Lv, Quanjian; Fan, Xuesen; Qu, Guirong
Journal of Chemical Research, 2008 , # 6 p. 357 - 360
