5,5-二甲基-1,3-环己二酮合成路线 （共 504 条）
反应条件
in xylene
3 h; Heating;
参考文献
Greenhill, John V.; Moten, M. Ashraf; Hanke, Reiner
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 2 p. 287 - 290
反应条件
sodium hydroxide; hydrazine hydrate; diethylene glycol
Reagens 4:Methanol;
参考文献
Bar-Tana, Jacob; Ben-Shoshan, Shoshana; Blum, Jochanan; Migron, Yoelit; Hertz, Rachel; et al.
Journal of Medicinal Chemistry, 1989 , vol. 32, # 9 p. 2072 - 2084
反应条件
[bis(acetoxy)iodo]benzene in acetonitrile
T=0°C; 2 h;
参考文献
Karade; Shirodkar; Patil; Potrekar
Tetrahedron Letters, 2003 , vol. 44, # 35 p. 6729 - 6731
反应条件
toluene-4-sulfonic acid in xylene
Heating;
参考文献
Greenhill, John V.; Moten, Mohammad Ashraf; Hanke, Reiner
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 6 p. 1213 - 1218
反应条件
ammonium cerium(IV) nitrate in methanol
Cyclization; oxidative addition; cooling;
参考文献
Nair; Balagopal; Mathew
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2000 , vol. 39, # 5 p. 352 - 356
反应条件
pyrrolidine in tetrahydrofuran
T=20°C; 36 h; regioselective reaction;
参考文献
Chawla, Ruchi; Singh, Atul K.; Yadav, Lal Dhar S.
Tetrahedron Letters, 2012 , vol. 53, # 26 p. 3382 - 3384
反应条件
tetraethylammonium p-toluenesulfonate in acetonitrile
carbon rod anode, platinum plate cathode, constant current (10 mA); other 1,3-diketones and olefines, var. solvents, var. electrolyte; Mechanism;
参考文献
Yoshida, Jun-ichi; Sakaguchi, Kazuhiko; Isoe, Sachihiko
Journal of Organic Chemistry, 1988 , vol. 53, # 11 p. 2525 - 2533
反应条件
1: 95 percent / CH2Cl2 / 1.5 h / 20 °C
2: 96 percent / acetonitrile / UV-irradiation
View Scheme
参考文献
Kalpogiannaki, Dimitra; Martini, Catherine-Irene; Nikopoulou, Aggeliki; Nyxas, John A.; Pantazi, Vassiliki; Hadjiarapoglou, Lazaros P.
Tetrahedron, 2013 , vol. 69, # 5 p. 1566 - 1575
反应条件
1: 86 percent / acetonitrile / 20 h / 20 °C
2: 72 h / Heating
3: 1 molar aq. NaHSO4 / 1 h
View Scheme
参考文献
Weidner, Juergen; Vilsmaier, Elmar; Fries, Ralf
Monatshefte fuer Chemie, 1987 , vol. 118, p. 1039 - 1056
反应条件
1: 54 percent / acetonitrile / 24 h / Ambient temperature
2: 73 percent / 150 °C / 0 Torr
View Scheme
参考文献
Vilsmaier, Elmar; Joerg, Klaus
Chemische Berichte, 1984 , vol. 117, # 9 p. 2910 - 2927
