5,11-二氢-11,11-二甲基茚并[1,2-b]咔唑合成路线 （共 8 条）
反应条件
triethyl phosphite in 1,2-dichloro-benzene T=140°C; 12 h;
参考文献
ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD.; LEE, Mi-ja; CHO, Young-jun
Patent: WO2012/169821 A1, 2012 ;
Location in patent: Page/Page column 18 ;
反应条件
triphenylphosphine in 1,2-dichloro-benzene Cadogan-Cameron Wood Cyclization; 24 h; Reflux;
参考文献
ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD.; AHN, Hee-Choon; LEE, Hyo-Jung; LEE, Mi-Ja; YANG, Soo-Jin; KIM, Chi-Sik; LEE, Su-Hyun; KIM, Hee-Sook; SHIN, Hyo-Nim; PARK, Kyoung-Jin; LEE, Kyung-Joo; KWON, Hyuck-Joo; KIM, Bong-Ok
Patent: WO2013/122402 A1, 2013 ;
Location in patent: Paragraph 153; 156; 157 ;
反应条件
1: palladium diacetate / toluene; 1,4-dioxane; ethanol; water 2: triethyl phosphite View Scheme
参考文献
Jung, Su Jin; Kim, Won Sam; Park, Byung Sun; Lee, Jae Kyun; Park, Jung Hwan; Choi, Kihang; Lee, So Ha
Heteroatom Chemistry, 2013 , vol. 24, # 1 p. 18 - 24
反应条件
1: palladium diacetate / toluene; 1,4-dioxane; ethanol; water 2: triethyl phosphite View Scheme
参考文献
Jung, Su Jin; Kim, Won Sam; Park, Byung Sun; Lee, Jae Kyun; Park, Jung Hwan; Choi, Kihang; Lee, So Ha
Heteroatom Chemistry, 2013 , vol. 24, # 1 p. 18 - 24
反应条件
1: potassium carbonate / tetrakis(triphenylphosphine) palladium(0) / water; tetrahydrofuran / 24 h / Inert atmosphere; Reflux 2: triphenylphosphinepalladium / 1,2-dichloro-benzene / 24 h / Reflux View Scheme
参考文献
Duksan Hi-Metal Co., Ltd.
Patent: EP2415773 A2, 2012 ;
反应条件
1: potassium carbonate / tetrakis(triphenylphosphine) palladium(0) / water; tetrahydrofuran / 24 h / Inert atmosphere; Reflux 2: triphenylphosphinepalladium / 1,2-dichloro-benzene / 24 h / Reflux View Scheme
参考文献
Duksan Hi-Metal Co., Ltd.
Patent: EP2415773 A2, 2012 ;
反应条件
1: boric acid trimethyl ester; n-butyllithium 2: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 24 h / |Reflux 3: triphenylphosphine / 1,2-dichloro-benzene / 24 h / |Reflux View Scheme
参考文献
Jung, Su Jin; Kim, Won Sam; Park, Byung Sun; Lee, Jae Kyun; Park, Jung Hwan; Choi, Kihang; Lee, So Ha
Heteroatom Chemistry, 2013 , vol. 24, # 1 p. 18 - 24
反应条件
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene; ethanol; water / 6 h / 120 °C 2: triethyl phosphite / 1,2-dichloro-benzene / 20 h / 160 °C View Scheme
参考文献
ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD.; AHN, Hee-Choon; LEE, Hyo-Jung; LEE, Mi-Ja; YANG, Soo-Jin; KIM, Chi-Sik; LEE, Su-Hyun; KIM, Hee-Sook; SHIN, Hyo-Nim; PARK, Kyoung-Jin; LEE, Kyung-Joo; KWON, Hyuck-Joo; KIM, Bong-Ok
Patent: WO2013/122402 A1, 2013 ;
