1,1-(2,2-二甲基-4,4-联苯二yl)双(3,6-二甲基-9h-咔唑)合成路线 （共 5 条）
反应条件
18-crown-6 ether; copper; potassium carbonate in 1,2-dichloro-benzene Ullmann condensation; 24 h; RefluxInert atmosphere;
参考文献
Schroegel, Pamela; Tomkeviciene, Ausra; Strohriegl, Peter; Hoffmann, Sebastian T.; Koehler, Anna; Lennartz, Christian
Journal of Materials Chemistry, 2011 , vol. 21, # 7 p. 2266 - 2273
反应条件
1: palladium 10 on activated carbon / 1,2,4-trimethyl benzene / 6 h / Reflux 2: 18-crown-6 ether; copper; potassium carbonate / 1,2-dichloro-benzene / 24 h / Reflux; Inert atmosphere View Scheme
参考文献
Schroegel, Pamela; Tomkeviciene, Ausra; Strohriegl, Peter; Hoffmann, Sebastian T.; Koehler, Anna; Lennartz, Christian
Journal of Materials Chemistry, 2011 , vol. 21, # 7 p. 2266 - 2273
反应条件
1: acetic acid / 0.5 h / 80 °C / Inert atmosphere 2: palladium 10 on activated carbon / 1,2,4-trimethyl benzene / 6 h / Reflux 3: 18-crown-6 ether; copper; potassium carbonate / 1,2-dichloro-benzene / 24 h / Reflux; Inert atmosphere View Scheme
参考文献
Schroegel, Pamela; Tomkeviciene, Ausra; Strohriegl, Peter; Hoffmann, Sebastian T.; Koehler, Anna; Lennartz, Christian
Journal of Materials Chemistry, 2011 , vol. 21, # 7 p. 2266 - 2273
反应条件
1.1: hydrogenchloride; sodium nitrite / water / 0 - 5 °C 1.2: 5 - 20 °C 2.1: 18-crown-6 ether; copper; potassium carbonate / 1,2-dichloro-benzene / 24 h / Reflux; Inert atmosphere View Scheme
参考文献
Schroegel, Pamela; Tomkeviciene, Ausra; Strohriegl, Peter; Hoffmann, Sebastian T.; Koehler, Anna; Lennartz, Christian
Journal of Materials Chemistry, 2011 , vol. 21, # 7 p. 2266 - 2273
反应条件
1: acetic acid / 0.5 h / 80 °C / Inert atmosphere 2: palladium 10 on activated carbon / 1,2,4-trimethyl benzene / 6 h / Reflux 3: 18-crown-6 ether; copper; potassium carbonate / 1,2-dichloro-benzene / 24 h / Reflux; Inert atmosphere View Scheme
参考文献
Schroegel, Pamela; Tomkeviciene, Ausra; Strohriegl, Peter; Hoffmann, Sebastian T.; Koehler, Anna; Lennartz, Christian
Journal of Materials Chemistry, 2011 , vol. 21, # 7 p. 2266 - 2273
