dipotassium hydrogenphosphate; Fremy’s salt in water; acetone 4 h;

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '4122952', constants.ctx, '0')">sodium hydride</a>;&nbsp;<a href="#" onclick="return RXDsubstances(event, this, '773638', constants.ctx, '0')">ethanethiol</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '605365', constants.ctx, '0')">N,N-dimethyl-formamide</a> <br />T=150&deg;C;&nbsp;3&nbsp;h;&nbsp;<br /> &nbsp;

<b>Multi-step reaction with 9 steps<br /> </b>1: 81 percent / P₂O₅, H₃PO₄ / CH₂Cl₂ / 0.33 h / 70 - 80 &deg;C<br />2: 69 percent / Zn / tetrahydrofuran / 2 h<br />3: 62 percent / Pd-black / 2 h / 280 - 300 &deg;C<br />4: 1) Mg / 1) Et₂O, 30 min 2) Et₂O, 3h<br />5: P₂O₅, H₃PO₄ / 0.5 h / 60 - 70 &deg;C<br />6: 80 percent / pyridinium chlorochromate / CH₂Cl₂ / 96 h / Ambient temperature<br />7: 82 percent / NaBH₄ / ethanol / 1 h / Ambient temperature<br />8: 42 percent / CH₃SO₂Cl, Et₃N / CH₂Cl₂ / 0 &deg;C<br />9: 77 percent / NaH, EtSH / dimethylformamide / 3 h / 150 &deg;C<br /> <br /> &nbsp;

<b>Multi-step reaction with 7 steps<br /> </b>1: 62 percent / Pd-black / 2 h / 280 - 300 &deg;C<br />2: 1) Mg / 1) Et₂O, 30 min 2) Et₂O, 3h<br />3: P₂O₅, H₃PO₄ / 0.5 h / 60 - 70 &deg;C<br />4: 80 percent / pyridinium chlorochromate / CH₂Cl₂ / 96 h / Ambient temperature<br />5: 82 percent / NaBH₄ / ethanol / 1 h / Ambient temperature<br />6: 42 percent / CH₃SO₂Cl, Et₃N / CH₂Cl₂ / 0 &deg;C<br />7: 77 percent / NaH, EtSH / dimethylformamide / 3 h / 150 &deg;C<br /> <br /> &nbsp;

<b>Multi-step reaction with 4 steps<br /> </b>1: 80 percent / pyridinium chlorochromate / CH₂Cl₂ / 96 h / Ambient temperature<br />2: 82 percent / NaBH₄ / ethanol / 1 h / Ambient temperature<br />3: 42 percent / CH₃SO₂Cl, Et₃N / CH₂Cl₂ / 0 &deg;C<br />4: 77 percent / NaH, EtSH / dimethylformamide / 3 h / 150 &deg;C<br /> <br /> &nbsp;

<b>Multi-step reaction with 6 steps<br /> </b>1: 1) Mg / 1) Et₂O, 30 min 2) Et₂O, 3h<br />2: P₂O₅, H₃PO₄ / 0.5 h / 60 - 70 &deg;C<br />3: 80 percent / pyridinium chlorochromate / CH₂Cl₂ / 96 h / Ambient temperature<br />4: 82 percent / NaBH₄ / ethanol / 1 h / Ambient temperature<br />5: 42 percent / CH₃SO₂Cl, Et₃N / CH₂Cl₂ / 0 &deg;C<br />6: 77 percent / NaH, EtSH / dimethylformamide / 3 h / 150 &deg;C<br /> <br /> &nbsp;

<b>Multi-step reaction with 12 steps<br /> </b>1: 87 percent / 20percent aq. NaOH / 2 h / Heating<br />2: 53 percent / AlCl₃ / nitrobenzene / Ambient temperature<br />3: 53 percent / Zn, HgCl₂, conc. HCl / H₂O; toluene / 24 h / Heating<br />4: 81 percent / P₂O₅, H₃PO₄ / CH₂Cl₂ / 0.33 h / 70 - 80 &deg;C<br />5: 69 percent / Zn / tetrahydrofuran / 2 h<br />6: 62 percent / Pd-black / 2 h / 280 - 300 &deg;C<br />7: 1) Mg / 1) Et₂O, 30 min 2) Et₂O, 3h<br />8: P₂O₅, H₃PO₄ / 0.5 h / 60 - 70 &deg;C<br />9: 80 percent / pyridinium chlorochromate / CH₂Cl₂ / 96 h / Ambient temperature<br />10: 82 percent / NaBH₄ / ethanol / 1 h / Ambient temperature<br />11: 42 percent / CH₃SO₂Cl, Et₃N / CH₂Cl₂ / 0 &deg;C<br />12: 77 percent / NaH, EtSH / dimethylformamide / 3 h / 150 &deg;C<br /> <br /> &nbsp;

<b>Multi-step reaction with 11 steps<br /> </b>1: 53 percent / AlCl₃ / nitrobenzene / Ambient temperature<br />2: 53 percent / Zn, HgCl₂, conc. HCl / H₂O; toluene / 24 h / Heating<br />3: 81 percent / P₂O₅, H₃PO₄ / CH₂Cl₂ / 0.33 h / 70 - 80 &deg;C<br />4: 69 percent / Zn / tetrahydrofuran / 2 h<br />5: 62 percent / Pd-black / 2 h / 280 - 300 &deg;C<br />6: 1) Mg / 1) Et₂O, 30 min 2) Et₂O, 3h<br />7: P₂O₅, H₃PO₄ / 0.5 h / 60 - 70 &deg;C<br />8: 80 percent / pyridinium chlorochromate / CH₂Cl₂ / 96 h / Ambient temperature<br />9: 82 percent / NaBH₄ / ethanol / 1 h / Ambient temperature<br />10: 42 percent / CH₃SO₂Cl, Et₃N / CH₂Cl₂ / 0 &deg;C<br />11: 77 percent / NaH, EtSH / dimethylformamide / 3 h / 150 &deg;C<br /> <br /> &nbsp;