反应条件
catalyst: lithium tert-butoxide in neat (no solvent) Kinetics; soln. of lithium tert-butoxide in DMMA (according to the method described by Shapiro, I. O. et al., Izv. Akad. Nauk LatvSSR, Ser. Khim., 535 (1964)); isotope exchange react. with Cr-complex at 25°C in evacuated glass ampuls; stopping the react. by pouring into cold acidified H2O, filtration (glass filter), washing of pptn. with H2O, distn. in vac., detn. of deuterium content by cobustion of the substrate in a quartz tube under O2;
参考文献
Antonova, M. V.; Moiseev, S. K.; Kalinin, V. N.; Shapiro, I. O.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1989 , vol. 38, # 11.1 p. 2256 - 2259
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1989 , # 11 p. 2458 - 2461
