2-苯基-3-丁炔-2-醇合成路线 （共 43 条）
反应条件
hydrogen in methanol T=20°C; 5 h; chemoselective reaction;
参考文献
Takahashi, Tohru; Yoshimura, Masatoshi; Suzuka, Hiroyasu; Maegawa, Tomohiro; Sawama, Yoshinari; Monguchi, Yasunari; Sajiki, Hironao
Tetrahedron, 2012 , vol. 68, # 39 p. 8293 - 8299
反应条件
hydrogen in 1,4-dioxane T=20°C; 24 h; chemoselective reaction;
参考文献
Sajiki, Hironao; Mori, Shigeki; Ohkubo, Tomoyuki; Ikawa, Takashi; Kume, Akira; Maegawa, Tomohiro; Monguchi, Yasunari
Chemistry - A European Journal, 2008 , vol. 14, # 17 p. 5109 - 5111
反应条件
sulfuric acid; water; mercury(II) oxide in tetrahydrofuran T=60°C; 2 h;
参考文献
Jirkovski, Ivo; Cayen, Mitchell, N.
Journal of Medicinal Chemistry, 1982 , vol. 25, # 10 p. 1154 - 1156
反应条件
polystyrene-supported N-heterocyclic carbene–silver complex T=40°C; P=37503.8 Torr; 24 h; Autoclave;
参考文献
Ca', Nicola Della; Gabriele, Bartolo; Ruffolo, Giuseppe; Veltri, Lucia; Zanetta, Tito; Costa, Mirco
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 1 p. 133 - 146
反应条件
1: 1.) zinc chloride, 2.) perchloric acid / 1.) 20 deg C, 3 h, 2.) ether 2: 90 percent / ammonium hydroxide / acetone View Scheme
参考文献
Dzhemilev, U. M.; Selimov, F. A.; Rutman, O. G.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1988 , vol. 37, # 11 p. 2343 - 2346
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1988 , # 11 p. 2600 - 2604
反应条件
mer,trans-[(CH3CH2CH2N(CH2CH2PPh2)2)RuCl2(PPh3)]; water 1.) THF, reflux, 2.) THF; Multistep reaction;
参考文献
Welby, Christine E.; Eschemann, Thomas O.; Unsworth, Christopher A.; Smith, Elizabeth J.; Thatcher, Robert J.; Whitwood, Adrian C.; Lynam, Jason M.
European Journal of Inorganic Chemistry, 2012 , # 9 p. 1493 - 1506
反应条件
trans-[RuCl2(η3:η3-2,7-dimethylocta-2,6-diene-1,8-diyl)(PPh3)] in water T=60°C; 24 h; Sealed tubeInert atmosphere;
参考文献
Cadierno, Victorio; Francos, Javier; Gimeno, Jose
Organometallics, 2011 , vol. 30, # 4 p. 852 - 862
反应条件
sodium hydride in tetrahydrofuran; N,N-dimethyl-formamide
T=20°C; 2 h;
参考文献
Clavier, Herve; Nolan, Steven P.
Chemistry - A European Journal, 2007 , vol. 13, # 28 p. 8029 - 8036
反应条件
1.1: HgO; H2SO4
2.1: NaH / tetrahydrofuran / 65 °C
2.2: aq. HCl / dioxane / 20 °C
3.1: LiOH*H2O / tetrahydrofuran; methanol / 20 °C
View Scheme
参考文献
Jirkovski, Ivo; Cayen, Mitchell, N.
Journal of Medicinal Chemistry, 1982 , vol. 25, # 10 p. 1154 - 1156
反应条件
1.1: HgO; H2SO4
2.1: NaH / tetrahydrofuran / 65 °C
2.2: aq. HCl / dioxane / 20 °C
View Scheme
参考文献
Jirkovski, Ivo; Cayen, Mitchell, N.
Journal of Medicinal Chemistry, 1982 , vol. 25, # 10 p. 1154 - 1156
