3-(4-甲氧基-3-(4,4,5,5-四甲基-1,3,2-二噁硼烷-2-基)苯基)丙酸甲酯合成路线 （共 3 条）
反应条件
1: With potassium acetate in cyclopentylmethyl ether 1 h; Inert atmosphere; 2: With X-Phos; palladium diacetate in cyclopentylmethyl ether T=80°C; 22 h; Inert atmosphere;
参考文献
MERCK SHARP and DOHME CORP.; THOMPSON, Christopher, F.; SWEIS, Ramzi, F.
Patent: WO2011/28395 A1, 2011 ;
Location in patent: Page/Page column 20-21 ;
反应条件
potassium acetate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct in 1,4-dioxane; dimethyl sulfoxide T=50 - 80°C; 17 h; Inert atmosphere;
参考文献
Shao, Pengcheng Patrick; Sun, Wanying; Katipally, Revathi Reddy; Vachal, Petr; Ye, Feng; Liu, Jian; Sha, Deyou
Patent: US2013/109649 A1, 2013 ;
Location in patent: Paragraph 0271; 0272 ;
反应条件
1: iodine; silver sulphate / methanol / 1 h / 20 °C 2: potassium acetate / dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct / 1,4-dioxane; dimethyl sulfoxide / 17 h / 50 - 80 °C / Inert atmosphere View Scheme
参考文献
Shao, Pengcheng Patrick; Sun, Wanying; Katipally, Revathi Reddy; Vachal, Petr; Ye, Feng; Liu, Jian; Sha, Deyou
Patent: US2013/109649 A1, 2013 ;
