in acetonitrile addn. of Zn complex to soln. of ferrocene derivative in CH3CN at room temp., strirred for 45 min at room temp., addn. of soln. of FeCl3*6H2O, stirred for 20 min; extraction with CH2Cl2, dried (MgSO4), evapn. of solvent, chromy. (silica gel / CCl4/Et2O: 5/2);
参考文献
Zeynizadeh, Behzad
Bulletin of the Chemical Society of Japan, 2003 , vol. 76, # 2 p. 317 - 326
in ethanol; water soln. of Fe complex in EtOH was added dropwise to soln. of NaBH4 in H2O at room temp.; stirred at room temp. overnight; poured into H2O; filtered (vac.); washed; dried;
参考文献
Sheridan, Matthew V.; Lam, Kevin; Geiger, William E.
Journal of the American Chemical Society, 2013 , vol. 135, # 8 p. 2939 - 2942
Carroll, Michael A.; White, Andrew J.P.; Widdowson, David A.; Williams, David J.
Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 10 p. 1551 - 1557
Carroll, Michael A.; White, Andrew J.P.; Widdowson, David A.; Williams, David J.
Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 10 p. 1551 - 1557
hydrogenchloride; sodium hydroxide; ammonium acetate in methanol; diethyl ether; water
redn. of ferrocene with NaBH4 in boiling abs. MeOH contg. AcONH4 for 6 h (N2); removal of solvent, addn. of water (pH 8-9, NaOH); extn. of free base with Et2O, drying; treatment with dry Et2O satd. with dry HCl gas; recrystn. from abs. MeOH, briefly treated with dry HCl gas; elem. anal.;
参考文献
Neuse, Eberhard W.; Meirim, Maria G.; Blom, Norman F.
Organometallics, 1988 , vol. 7, p. 2562 - 2565
