1279123-63-5合成路线 （共 36 条）
反应条件
in neat (no solvent)
heating a mixture of As2O3 and KHF2;;
参考文献
Gmelin Handbook: As: MVol., 134, page 359 - 361
反应条件
in neat (no solvent)
byproducts: C5H11OH; heating equimolar mixt. of (C5H11O)3As and KF*HF;;
参考文献
Fofanova, E. L.; Gavrilov, V. I.; Garieva, F. R.; Musin, R. Z.
Journal of General Chemistry USSR (English Translation), 1992 , vol. 62, p. 922 - 924
Zhurnal Obshchei Khimii, 1992 , vol. 62, p. 1127 - 1129
反应条件
PdCl(C6H4C6H4NH2)(Cy2PC6H4-2-C6H2-2',4',6'-i-Pr3); Cy2PC6H4-2-C6H2-2',4',6'-i-Pr3; K acetate in ethanol
aryl chloride reacted with B2(OH)4 in EtOH in presence of catalyst (Pt-complex - ligand) and K acetate at 80°C for 2 h; subjected to aq. workup; treated with KHF2; purified by Soxlet extn.;
参考文献
Molander, Gary A.; Trice, Sarah L. J.; Kennedy, Steven M.; Dreher, Spencer D.; Tudge, Matthew T.
Journal of the American Chemical Society, 2012 , vol. 134, # 28 p. 11667 - 11673
反应条件
in tetrahydrofuran; water
boronic acid dissolved in THF; treated with aq. KHF2 (excess); stirred at room temp. overnight; THF removed under reduced pressure on rotary evaporator; H2O removed by lyophilization; extd. with acetone; combined extracts concd. under reduced pressure; residue washed with ether; elem. anal.;
参考文献
Smoum, Reem; Rubinstein, Abraham; Srebnik, Morris
Organic and Biomolecular Chemistry, 2005 , vol. 3, # 5 p. 941 - 944
反应条件
hydrogenchloride in methanol; diethyl ether; water
Mg compd. added to soln. of B compd. at -65--70°C dropwise within1.5 h, warmed to 20°C within 3 h, hydrolysed with aq. HCl, org. phase sepd., aq. phase extd. with ether, dried with MgSO4, dissolved in MeOH, reacted with aq. B compd.; after 5 min filtered, dried, extd. with hot acetone, solvent removed in vac., dried over P4O10, elem. anal.;
参考文献
Bardin; Idemskaya; Frohn
Zeitschrift fur Anorganische und Allgemeine Chemie, 2002 , vol. 628, # 4 p. 883 - 890
反应条件
500°C, in noble metal apparatus, thermal decompn., dried KHF2 must be used; distn.;
参考文献
Kwasnik, W.
G. Brauer, Handbuch der Paeparativen Anorganischen Chemie, Stuttgart 1975, pp.164/166
