(R)-4-(1-羟基乙基) 苯甲酸甲酯合成路线 (共 2 条)
反应条件
hydrogen; RuH(.eta.1-BH4)[(S)-2,2'-bis(di-3,5-xylylphosphino)-1,1'-binaphthyl][(S,S)-1,2-diphenylethylenediamine] in isopropyl alcohol T=23 - 25°C; P=6080.41 Torr; 15 h;
参考文献
Nagoya Industrial Science Research Institute
Patent: US6720439 B1, 2004 ;
Location in patent: Page/Page column 12-13 ;
反应条件
(3aS)-1-methyl-3, 3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole borane complex in dichloromethane T=-20°C; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Guo, Rongwei; Chen, Xuanhua; Elpelt, Christian; Song, Datong; Morris, Robert H.
Organic Letters, 2005 , vol. 7, # 9 p. 1757 - 1759