in dichloromethane

[Ni0(1,5-cyclooctadiene)2]; potassium phosphate; PCy3∙HBF4 in water; tert-butyl alcohol T=110°C; Suzuki-Miyaura cross coupling; 4 h; Inert atmosphere;

dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine; potassium phosphate; dichloro(cycloocta-1,5-diene)palladium(II) in water; tert-butyl alcohol T=95°C; Suzuki-Miyaura cross-coupling; 22 h; Inert atmosphere;

CM-phos; palladium diacetate; potassium carbonate in water; tert-butyl alcohol T=80°C; 18 h; Inert atmosphere;