(1R,5S)-3-氧杂二环[3.3.0]辛-6-烯-2-酮合成路线 （共 17 条）
反应条件
oxygen in water T=30°C; 2 h; biotransformation by Ps. putida NCIMB 10007 monooxygenase enzyme using NADPH as cofactor; further monooxygenases; pH 7.1; Yield given. Yields of byproduct given;
参考文献
Cavarzan, Alessandra; Bianchini, Giulio; Sgarbossa, Paolo; Lefort, Laurent; Gladiali, Serafino; Scarso, Alessandro; Strukul, Giorgio
Chemistry - A European Journal, 2009 , vol. 15, # 32 p. 7930 - 7939
反应条件
ethylenediaminetetraacetic acid; oxygen; Adenine-flavine dinucleotide; NADP in water T=30°C; Baeyer-Villiger oxidation reaction; pH=7.4; Irradiationkinetic resolution;
参考文献
Jensen, Chantel N.; Cartwright, Jared; Ward, Jonathan; Hart, Sam; Turkenburg, Johan P.; Ali, Sohail T.; Allen, Michael J.; Grogan, Gideon
ChemBioChem, 2012 , vol. 13, # 6 p. 872 - 878
反应条件
L(+)-arabinose T=20°C; Baeyer-Villiger oxidation; 24 h; LBamp mediumEnzymatic reaction; optical yield given as percent eestereoselective reaction;
参考文献
Baldwin, Christopher V.F.; Wohlgemuth, Roland; Woodley, John M.
Organic Process Research and Development, 2008 , vol. 12, # 4 p. 660 - 665
反应条件
phosphite dehydrogenase; Cyanidioschyzon merolae strain 10D (NIES-1332) Baeyer-Villiger monooxygenase; anhydrous phosphate; NADPH in 1,4-dioxane T=25°C; Baeyer-Villiger Ketone Oxidation; pH=7.5; Enzymatic reaction; Kinetics; Reagent/catalyst; regioselective reaction;
参考文献
Beneventi, Elisa; Niero, Mattia; Motterle, Riccardo; Fraaije, Marco; Bergantino, Elisabetta
Journal of Molecular Catalysis B: Enzymatic, 2013 , vol. 98, p. 145 - 154
反应条件
L(+)-arabinose T=20°C; Baeyer-Villiger oxidation; 24 h; LBamp mediumEnzymatic reaction; optical yield given as percent eestereoselective reaction;
参考文献
Torres Pazmino, Daniel E.; Snajdrova, Radka; Baas, Bert-Jan; Ghobrial, Michael; Mihovilovic, Marko D.; Fraaije, Marco W.
Angewandte Chemie - International Edition, 2008 , vol. 47, # 12 p. 2275 - 2278
反应条件
glycine-Na4P2O7 buffer; Sepharose-bound horse liver alhohol dehydrogenase; nicotinamide adenine dinucleotide; Flavin mononucleotide in water 22 h;
参考文献
Kajiwara, Tadahiko; Akakabe, Yoshihiko; Matsui, Kenji; Kodama, Kazuya; Koga, Harunobu; Nagakura, Takamitsu
Phytochemistry, 1997 , vol. 45, # 3 p. 529 - 532
反应条件
Acinetobacter calcoaceticus cyclohexanone monooxygenase; Thermoanaerobium brokii dehydrogenase; NADP in isopropyl alcohol enantiodivergent oxidation; pH=8.6; 24 h; Enzyme kineticsProduct distribution;
参考文献
Mihovilovic, Marko D.; Rudroff, Florian; Groetzl, Birgit; Kapitan, Peter; Snajdrova, Radka; Rydz, Joanna; Mach, Robert
Angewandte Chemie - International Edition, 2005 , vol. 44, # 23 p. 3609 - 3613
反应条件
culture of Acinetobacter
参考文献
Bianchini, Giulio; Cavarzan, Alessandra; Scarso, Alessandro; Strukul, Giorgio
Green Chemistry, 2009 , vol. 11, # 10 p. 1517 - 1520
反应条件
BVMO Rv3049c from Mycobacterium tuberculosis H37Rv; isopropyl 1-thio-β-D-galactopyranoside; β-cyclodextrin in water T=20°C; Baeyer-Villiger oxidation; 48 h; Title compound not separated from byproducts;
参考文献
Snajdrova, Radka; Grogan, Gideon; Mihovilovic, Marko D.
Bioorganic and Medicinal Chemistry Letters, 2006 , vol. 16, # 18 p. 4813 - 4817
反应条件
(1S,2S)-trans-1,2-cyclohexanediol in ethanol T=25°C; 5 h; Acinetobacter TD63;
参考文献
Alphand, Veronique; Furstoss, Roland
Journal of Organic Chemistry, 1992 , vol. 57, # 4 p. 1306 - 1309
