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1: Reaktion ueber mehrere Stufen 2: aluminium amalgam; water containing diethyl ether View Scheme

hydrogenchloride; [RuCl(benzene){(2,2,2',2'-tetramethyl[4,4'-bibenzo[d][1,3]dioxole]-5,5'-diyl)bis(diphenylphosphine)}]Cl; water; hydrogen in tetrahydrofuran P=20686.5 Torr; 5 h; Autoclave; optical yield given as percent eeenantioselective reaction;

1: (1R)-bornylamine 2: platinum; methanol / Hydrogenation View Scheme

1: (+/-)-2-hydroxy-4-phenylbut-3-enoic acid With hydrogenchloride; [RuCl(benzene){(2,2,2',2'-tetramethyl[4,4'-bibenzo[d][1,3]dioxole]-5,5'-diyl)bis(diphenylphosphine)}]Cl; water; hydrogen in tetrahydrofuran P=20686.5 Torr; 5 h; Autoclave; 2: ethanol With sulfuric acid 5 h; Inert atmosphereReflux; optical yield given as percent eeenantioselective reaction;

hydrogenchloride

[RuCl(benzene){(2,2,2',2'-tetramethyl[4,4'-bibenzo[d][1,3]dioxole]-5,5'-diyl)bis(diphenylphosphine)}]Cl; water; hydrogen iodide; hydrogen in tetrahydrofuran P=20686.5 Torr; 20 h; Autoclave; optical yield given as percent eeenantioselective reaction;

sulfuric acid; acetic anhydride