in tetrahydrofuran stirring ((C5H5)2Zr(CH2PMe2)2)2Ni (1.5 mmol) with ((CH3)3PH)Cl (6.0 mmol) for 2 h in THF at room temp.;; removal of solvent in vac.; sepn by extg. residue with pentane;;
参考文献
Journal of Organometallic Chemistry, , vol. 273, # 2 p. 195 - 212
in benzene-d6 byproducts: CH4, C6H5CH3; addn. of 2 equivs. of borane to dibenzylzirconocene, addn. of 2 equivs. of Cp2ZrHMe; not sepd.; NMR spectroscopy;
in benzene byproducts: Si(CH3)3P(C6H5)2; SiMe3Cl added to soln. of complex in C6H6 at room temp.; solvent removed, residue washed with n-hexane to give complex;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 2555 - 2560
in benzene byproducts: P(C6H5)2P(C6H5)2; PPh2Cl injected into soln. of complex, stirred for 3 min at room temp.; solv. removed in vac., solid extd. with n-hexane to leave Zr complex;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 2555 - 2560
in benzene byproducts: P(C6H5)2P(C6H5)2; AsPh2Cl injected into soln. of complex, stirred for 3 min at room temp.; solv. removed in vac., solid extd. with n-hexane to leave Zr complex;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 2555 - 2560
