in dichloromethane-d2 inert atmosphere, dry solvents, addn. of 4 equiv. of PMe3 to soln. of Zr-compd. in CD2Cl2; (1)H-NMR spectroscopic monitoring at 23°C;
in benzene-d6 (Cp2ZrH2) placed in NMR tube and suspended with a soln. of Cp2Zr(Cl)CPh2OCH3 in benzene-d6; mixt. heated at 55°C for 2 h;; not isolated; react. followed by NMR spectroscopy;;
参考文献
Journal of the American Chemical Society, , vol. 108, p. 2251
