4-溴苯基三氟甲基磺酸酯合成路线 （共 13 条）
反应条件
pyridine in dichloromethane T=0 - 20°C; Inert atmosphere;
参考文献
Prakash, Anjanappa; Dibakar, Mullick; Selvakumar, Kumaravel; Ruckmani, Kandasamy; Sivakumar, Manickam
Tetrahedron Letters, 2011 , vol. 52, # 43 p. 5625 - 5628
反应条件
pyridine; hydrogenchloride; trifluoromethanesulfonic acid anhydride in dichloromethane
参考文献
Matsumura, Kazuhiko; Saito, Takao
Patent: US2003/139285 A1, 2003 ;
反应条件
n-butyllithium in tetrahydrofuran T=-78°C; 0.166667 h;
参考文献
Matsumoto, Takashi; Hosoya, Takamitsu; Katsuki, Miyoko; Suzuki, Keisuke
Tetrahedron Letters, 1991 , vol. 32, # 46 p. 6735 - 6736
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; copper(l) iodide; palladium diacetate; triethylamine in N,N-dimethyl-formamide T=20°C; Sonogashira coupling; Inert atmosphere;
参考文献
Prakash, Anjanappa; Dibakar, Mullick; Selvakumar, Kumaravel; Ruckmani, Kandasamy; Sivakumar, Manickam
Tetrahedron Letters, 2011 , vol. 52, # 43 p. 5625 - 5628
反应条件
dichlorolt;(2-dimethylamino)propyldiphenylphosphinegt;palladium; lithium bromide in diethyl ether; toluene T=20°C; 4 h;
参考文献
Kamikawa, Takashi; Hayashi, Tamio
Journal of Organic Chemistry, 1998 , vol. 63, # 24 p. 8922 - 8925
反应条件
1: copper(l) iodide; 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; triethylamine / N,N-dimethyl-formamide / 20 °C / Inert atmosphere 2: palladium diacetate; (S)-(-)-2-methyl-2-propanesulfinamide; caesium carbonate; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene / 1,4-dioxane / 15 h / 100 °C / Inert atmosphere View Scheme
参考文献
Prakash, Anjanappa; Dibakar, Mullick; Selvakumar, Kumaravel; Ruckmani, Kandasamy; Sivakumar, Manickam
Tetrahedron Letters, 2011 , vol. 52, # 43 p. 5625 - 5628
反应条件
sodium carbonate; tetrakis(triphenylphosphine) palladium(0) in ethylene glycol dimethyl ether Heating;
参考文献
Tetrahedron Letters, , vol. 31, # 12 p. 1665 - 1668
反应条件
caesium carbonate in toluene T=130°C; 15 h;
参考文献
Green, Alice E.; Agouridas, Vangelis; Deniau, Eric
Tetrahedron Letters, 2013 , vol. 54, # 51 p. 7078 - 7079
反应条件
Pd(1,3-bis(diphenylphosphino)-propane)Cl2 in diethyl ether T=20°C; 12 h; Title compound not separated from byproducts;
参考文献
Tetrahedron Letters, , vol. 38, # 40 p. 7087 - 7090
反应条件
1: 2-(trifluoromethanesulfonyl)oxy-bromobenzene; immobilized on REM resin N-acetyldehydroalanine With N,N-dicyclohexylmethylamine; [(t-Bu)3PH]BF4; tris(dibenzylideneacetone)dipalladium(0) chloroform complex in ethylene glycol dimethyl ether T=100°C; Heck reaction; 2: methanol With sodium methylate in tetrahydrofuran T=20°C; 16 h; Further stages.;
参考文献
Journal of the Chemical Society. Perkin Transactions 1, , # 19 p. 2137 - 2138
