双(1,5-环辛二烯)镍(0)合成路线 （共 74 条）
反应条件
diisobutylaluminium hydride in tetrahydrofuran; toluene T=-78 - 0°C; 1 h; HeatingInert atmosphere;
参考文献
Tetrahedron, , vol. 69, # 27-28 p. 5609 - 5613
反应条件
dibutylmagnesium in tetrahydrofuran to soln. (NiCl2(py)4) in THF COD was added, mixt. was cooled in liquid N2-EtOH bath, Bu2Mg in THF was added dropwise and stirred for 1 h at roomtemp.; solvent was removed in vacuo, residue was washed with MeOH and filtered,ppt. waswashed with MeOH, EtOH, light petroleum, and dried in vacuo;
参考文献
Tenorio, Manuel Jimenez; Puerta, M. Carmen; Salcedo, Isabel; Valegra, Pedro
Journal of the Chemical Society, Dalton Transactions, 2001 , p. 653 - 657
反应条件
in pyridine Electrolysis; 0°C, between aluminium electrodes, 18 V, 2 mA/cm2;
参考文献
Lehmkuhl; Leuchte
Journal of Organometallic Chemistry, 1970 , vol. 23, p. C30
Full Text View citing articles Show Details
Gmelin Handbook: Ni: Org.Verb.2, 1.4.2.1.1, page 87 - 88
反应条件
in benzene molar ratio nickel acetylacetonat : cyclooctadiene = 1 : 2.5-5, benzene free from air, reduction between 0 and 5°C, 2 h, and room temp. 15 h;
参考文献
Gmelin Handbook: Ni: Org.Verb.2, 1.4.2.1.1, page 87 - 88
Full Text Show Details
Studiengesellschaft Kohle m.b.H.
Patent: DE1191375 , 1965 ;
反应条件
in diethyl ether under Ar; reaction with 1 equiv of P(OC6H4-o-Ph)3 at -30°C to room temp.;
参考文献
Benn, R.; Buessemeier, B.; Holle, S.; Jolly, P. W.; Mynott, R.; et all.
Journal of Organometallic Chemistry, 1985 , vol. 279, p. 63 - 86
反应条件
Electrolysis; nickel anode;
参考文献
Lehmkuhl; Leuchte
Journal of Organometallic Chemistry, 1970 , vol. 23, p. C30
Full Text View citing articles Show Details
Gmelin Handbook: Ni: Org.Verb.2, 1.4.2.1.1, page 87 - 88
反应条件
in diethyl ether a suspn. of Ni-complex in ether was treated with COD at -78°C under Ar; ppt. was filtered off, washed with cold ether, dried at 20°C under vac.; IR identification;
参考文献
Schroeder, Wolfgang; Poerschke, Klaus R.
Journal of Organometallic Chemistry, 1987 , vol. 322, p. 385 - 392
参考文献
Porschke, Klaus Richard; Wilke, Gunther
Journal of Organometallic Chemistry, 1988 , vol. 349, p. 257 - 262
反应条件
1,5-cyclooctadiene in tetrahydrofuran byproducts: C2H4; -30°C, under Ar;
参考文献
Chemische Berichte, , vol. 118, # 1 p. 275 - 297
参考文献
Angewandte Chemie, , vol. 85, p. 620 - 621
Diss. Bochum 1973
