(3R,6R)-3,6-辛二醇合成路线 （共 12 条）
反应条件
potassium carbonate in methanol; water T=20°C; 72 h; Inert atmosphere;
参考文献
Tetrahedron Letters, , vol. 50, # 26 p. 3237 - 3240
反应条件
sodium methylate in methanol T=0°C; electrochemical coupling, pH 5.38;
参考文献
Tetrahedron Asymmetry, , vol. 2, # 7 p. 569 - 592
反应条件
dimethylsulfide borane complex; (S)-B-methyl-4,5,5-triphenyl-1,3,2-oxazaborolidine in tetrahydrofuran T=0°C; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tetrahedron Letters, , vol. 38, # 6 p. 1091 - 1094
反应条件
1: oxidation 2: H2 / Pd/C / methanol 3: BH3*SMe2 / (S)-B-methyl-4,5,5-triphenyl-1,3,2-oxazaborolidine / tetrahydrofuran / 0 °C View Scheme
参考文献
Tetrahedron Letters, , vol. 38, # 6 p. 1091 - 1094
反应条件
1: H2 / Pd/C / methanol 2: BH3*SMe2 / (S)-B-methyl-4,5,5-triphenyl-1,3,2-oxazaborolidine / tetrahydrofuran / 0 °C View Scheme
参考文献
Tetrahedron Letters, , vol. 38, # 6 p. 1091 - 1094
反应条件
1: NaBH4 / ethanol 2: H2 / Pt/C / methanol View Scheme
参考文献
Tetrahedron Letters, , vol. 38, # 6 p. 1091 - 1094
反应条件
hydrogen; platinum on activated charcoal in methanol Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tetrahedron Letters, , vol. 38, # 6 p. 1091 - 1094
反应条件
hydrogen; platinum on activated charcoal in methanol Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tetrahedron Letters, , vol. 38, # 6 p. 1091 - 1094
反应条件
1: 100 percent / H2, <Ru((R)-(+)-BINAP> cat. / methanol; CH2Cl2 / 48 h / 25 °C / 77572.2 Torr 2: 97 percent / aq. KOH / ethanol / 48 h / 25 °C 3: 36 percent / NaOMe / methanol / 0 °C / electrochemical coupling, pH 5.38 View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 2, # 7 p. 569 - 592
反应条件
1: 97 percent / aq. KOH / ethanol / 48 h / 25 °C 2: 36 percent / NaOMe / methanol / 0 °C / electrochemical coupling, pH 5.38 View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 2, # 7 p. 569 - 592
